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有机化学
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有机化学 ›› 1986, Vol. 6 ›› Issue (6): 449-453. 上一篇    下一篇

研究论文

(μR-RS)(μ-XMgS)Fe~2(CO)~6与取代丙烯酸酯的加成反应-甲基取代的酯乙基铁硫络合物的合成

宋礼成;胡青眉;沈力红;王积涛   

  1. 南开大学化学系
  • 发布日期:1986-12-25

Addition reactions of (\m\-RS)(\m\-XMgS)Fe~2(CO)~6wiwth substitutd acrylates--synthesis of methyl substituted alkoxycarbonylethyl Fe-S complexes

SONG LICHENG;HU QINGMEI;SHEN LIHONG;WANG JITAO   

  • Published:1986-12-25

被引次数

3

通过硫镁络合物(μ-RS)(μ-XMgS)Fe2(CO)6分别与反式-巴豆酸乙酯,α-甲基丙烯酸甲酯的加成-醇解反应,合成了十三个甲基取低的酯乙基铁硫络合物.这些新络合物的结构的结构均经元素分析,IR及^HNMR谱确证.

关键词: 丙烯酸酯 P, 硫络合物, 铁络合物, 加成反应, 簇状化合物

Reaction of Fe2(CO)6(m-RS)(m-XMgS) with trans-Et crotonate and Me methacrylate sep., followed by alcoholysis of the intermediates formed, gave (m-RS)(m-EtO2CCH2C(Me)HS)Fe2(CO)6 and (m-RS)(m-MeO2CC(Me)HCH2S)Fe2(CO)8, resp. These complexes were characterized by elemental anal., IR and 1H NMR spectroscopy.

Key words: IRON COMPLEX, CLUSTER COMPOUND, ADDITION REACTION, SULFIDE COMPLEX, PROPENOIC ACID ESTER P

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