有机化学 ›› 1987, Vol. 7 ›› Issue (6): 409-417.    下一篇

研究论文

不对称环丙烷化反应

黄乃正;陈展荣;侯雪龙   

  1. 香港中文大学化学系;中国科学院上海有机化学研究所
  • 发布日期:1987-12-25

Asymmetric cyclopropanation

HUANG NAIZHENG;CHIN WING CHAN;HUO XUELONG   

  • Published:1987-12-25

关键词: 重氮化合物, 环丙烷 P, 碳烯, 环丙甲酸 P, 三苯基膦, 异丙叉, 诱导效应, 环烷基化, 西蒙斯-史密斯反应, 不对称反应

A review with 26 refs. Asym. cyclopropanation reactions e.g. the Simmons-Smith reaction as well as catalyzed thermal decomposition of diazo-compds., isopropylidenetriphenylphosphine and some organometallic compounds were discussed. These methods are examplified by the synthesis of cyclopropanecarboxylic acids.4

Key words: DIAZO COMPOUNDS, CYCLOPROPANE P, CARBENE, CYCLOPROPANE CARBOXYLIC ACID P, TRIPHENYLPHOSPHINE, ISOPROPYLIDENE, INDUCTIVE EFFECT, CYCLOALKYLATION, SIMONS-SMITH REACTION

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