有机化学 ›› 1995, Vol. 15 ›› Issue (1): 95-99. 上一篇    下一篇

研究论文

锌和锡参与下末端环氧化物的选择性烯丙基化反应

邓道利;陆忠辉   

  1. 中国科学院上海有机化学研究所;中国科学院上海有机化学研究所
  • 发布日期:1995-02-25

Zinc- and tin-mediated selective allylation of terminal epoxides

DENG DAOLI   

  • Published:1995-02-25

烯丙基溴和金属辛或锡成功地将末端环氧化合物1一锅法合成高烯丙基醇2和双高烯丙基醇3. 还研究了环氧化合物取代基的影响, 并提出了此烯丙基化的反应途径 .

关键词: 锌, 锡, 环氧化物, 烯丙基化

Allylation of terminal epoxides 1 can be carried out successfully by allyl bromide and metallic zinc or tin in a novel one-pot synthesis to give the homoallylic alcohols 2 and bishomoallylic alcohlos 3. The effect of substituents on epoxides was studied. The reaction pathway of this allylation was also suggested.

Key words: ZINC, TIN, EPOXIDE, ALLYLATION

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