有机化学 ›› 2000, Vol. 20 ›› Issue (2): 255-257. 上一篇    下一篇

研究论文

N-(2-氯乙基)苯甲醛亚胺的Friedel - Crafts反应

陈林;包季全;姚子鹏   

  1. 云南民族学院化学系;复旦大学化学系.上海(200433)
  • 发布日期:2000-04-25

Friedel - crafts reaction of N - ( 2- chloroethyl) benzaldimine

Chen Lin;Bao Jiquan;Yao Zipeng   

  1. Fudan Univ, Dept Chem.Shanghai(200433)
  • Published:2000-04-25

研究了N-(2-氯乙基)苯甲醛亚胺与苯和甲苯的Friedel-Crafts烷基化反应,生成的亚胺(2),经酸水解生成2-芳乙胺(3)。

关键词: 苯甲醛P, 亚胺, Friedel-Crafts反应, 烷基化, 苯, 甲苯, 水解, 芳香族胺

The friedel -Cratfs reaction between N - (2 -chloroethyl) benzaldimines (1) with arenes (benzene, toluene) in the presence of aluminium trichloride was studied. Upon hydrolysis N - (2 - arylethyl) benaldimines (2) with 6 mol/L HCl, product 2 - arylethylamine (3) were obtained.

Key words: BENZALDEHYDE P, IMINE, ALKYLATION, BENZENE, METHYLBENZENE, HYDROLYSIS, AROMATIC AMINES

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