有机化学 ›› 2005, Vol. 25 ›› Issue (02): 167-175. 上一篇    下一篇

综述与进展

氮杂偶联加成反应的研究

徐利文,夏春谷*,吴乎格吉乐土,杨磊,周伟,张妍   

  1. (中国科学院兰州化学物理研究所 羰基合成与选择氧化国家重点实验室 兰州 730000)
  • 收稿日期:2004-03-11 修回日期:2004-06-29 发布日期:2005-01-15
  • 通讯作者: 夏春谷

Progress in Aza-Michael Reaction

XU Li-Wen,XIA Chun-Gu*,WU Hugjiltu,YANG Lei
ZHOU Wei,ZHANG Yan   

  1. (State Key Laboratory of Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Phys-ics,
    Chinese Academy of Sciences, Lanzhou 730000)
  • Received:2004-03-11 Revised:2004-06-29 Published:2005-01-15
  • Contact: XIA Chun-Gu

氮杂偶联加成反应是一类在近十年里才受到重视的原子经济性新反应, 尤其是在近几年里许多有效的合成方法不断被发展和研究. 系统总结了各种氮源参与的氮杂偶联加成反应的研究进展.

关键词: 氮杂偶联加成反应, 氮源, 胺, 羟胺, 氨基甲酸酯

Aza-Michael reaction was a novel atomic economy reaction and has attracted much attention in past ten years. In the past few years, a large number of effective procedures for this reaction have been developed. This review deals with the progress in aza-Michael reaction.

Key words: aza-Michael reaction, carbamate, nitrogen nucleophile, hydroxylamine, amine