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有机化学
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有机化学 ›› 2011, Vol. 31 ›› Issue (10): 1573-1581. 上一篇    下一篇

综述与进展

钯催化卤代芳烃的胺化反应的研究进展

方晒，吕梅香，龙玉华，杨定乔*   

  1. (华南师范大学化学与环境学院 广州 510006)
  • 收稿日期:2010-02-17 修回日期:2011-06-27 发布日期:2011-03-22
  • 通讯作者: 杨定乔 E-mail:yangdq@scnu.edu.cn
  • 基金资助:

    新型手性双膦配体设计合成及铱不对称催化开环反应研究

Progress in Palladium-Catalyzed Amination of Aryl Halides

FANG Shai, LV Mei-Xiang, LONG Yu-Hua, YANG Ding-Qiao   

  1. (School of Chemistry and Environment, South China Normal University, Guangzhou 510006)
  • Received:2010-02-17 Revised:2011-06-27 Published:2011-03-22
  • Contact: Yang Ding-qiao E-mail:yangdq@scnu.edu.cn

PDF

2593

被引次数

5 | 3

钯催化卤代芳烃的胺化是合成芳胺化合物的重要方法, 综述了近年来钯催化卤代芳烃与胺等不同含氮化合物的胺化反应研究进展, 重点讨论了钯催化剂配体的结构、反应物比例、溶剂及温度等因素对反应的影响.

关键词: 钯催化, 卤代芳烃, 胺化, 研究进展

Palladium-catalyzed amination of aryl halides is one of the most important methods for preparing aromatic amine compounds. The recent progress in palladium-catalyzed amination of aryl halides with amines and different nitrogen-containing compounds is reviewed. The main focuses are the effects on this kind of reaction, e.g. the structures of ligands, ratio of reactants, solvents, temperature, and etc.

Key words: palladium catalysis, aryl halide, amination, recent progress