有机化学 ›› 2013, Vol. 33 ›› Issue (12): 2496-2503.DOI: 10.6023/cjoc201306015 上一篇    下一篇

综述与进展

基于2,2’-联萘酚衍生物的荧光化学传感器对手性异构体选择性识别研究进展

杨丽a, 徐括喜a, 王晨娟a, 王超杰b   

  1. a 河南大学化学化工学院 河南大学精细化学与工程研究所 开封 475004;
    b 河南省天然药物与免疫工程重点实验室 开封 475004
  • 收稿日期:2013-06-09 修回日期:2013-07-24 发布日期:2013-08-16
  • 通讯作者: 徐括喜, 王超杰 E-mail:xukx@henu.edu.cn;wcjsxq@henu.edu.cn
  • 基金资助:

    国家自然科学基金(Nos. 20872027,90913001)、河南省科技厅(Nos. 132102210388,132300410055)资助项目.

Progress in Fluorescent Chemosensors for Chiral Enantiomer Recognition Based on 2,2’-Naphthol Derivatives

Yang Lia, Xu Kuoxia, Wang Chenjuana, Wang Chaojieb   

  1. a Institute of Fine Chemical and Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004;
    b Key Laboratory of Natural Medicine and Immuno-Engineering of Henan Province, Kaifeng 475004
  • Received:2013-06-09 Revised:2013-07-24 Published:2013-08-16
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 20872027, 90913001) and the Technological Project of Henan Province (Nos. 132102210388, 132300410055).

2,2’-联萘酚是一个具有光活性的轴手性化合物,近年来,它已成为构筑多种多样的手性化学传感器的基本骨架之一. 很多文献报道了近年来众多基于2,2’-联萘酚的荧光化学传感器被广泛的设计和合成并表现出对手性氨基酸、氨基醇,α-羟基羧酸及其衍生物和其他化合物表现出很高的选择性和灵敏度. 综述了以2,2’-联萘酚衍生物作为化学传感器在对手性异构体的选择性识别中的应用的最新的研究进展.

关键词: 手性异构体, 2,2’-联萘酚, 化学传感器, 荧光

Being an axial chiral compound with optical activity, 2,2'-naphthol (BINOL) has become one of the basic units for constructing various chiral fluorescent chemosensors in recent years. According to the literatures, chiral BINOL derivatives chemosensors carry out highly enantioselective, sensitive recognition of amino acid and its derivatives, chiral amino alcohols, and α-hydroxycarboxylic acids. In this progress, BINOL derivatives as enantioselective chemosensors for chiral enantiomers are summarized.

Key words: chiral enantiomer, 2,2’-naphthol, chemosensor, fluorescence