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有机化学 ›› 2014, Vol. 34 ›› Issue (4): 729-734.DOI: 10.6023/cjoc201311007 上一篇    下一篇

研究论文

含二氮杂萘砌块化合物的荧光性能构效关系研究及应用

魏永俊a,, 孟思妍a,, 张莉卓a, 王超a, 张家明b, 宛瑜c, 吴翚a,c   

  1. a 江苏师范大学化学化工学院 江苏省功能材料绿色合成重点实验室 徐州 221116;
    b 江苏省泗洪县教育局 泗洪 223900;
    c 江苏药用植物生物技术重点实验室 徐州 221116
  • 收稿日期:2013-11-05 修回日期:2013-12-17 发布日期:2014-01-02
  • 通讯作者: 吴翚 E-mail:wuhui72@yahoo.com.cn
  • 基金资助:

    江苏省高校自然科学研究重大项目（No. 10KJA430050）和江苏师范大学自然科学重点基金（No. 11XLA06）资助项目.

Study and Application of the Structure-Fluorescence Relationship of Naphthyridine-Containing Compounds

Wei Yongjuna,, Meng Siyana,, Zhang Lizhuoa, Wang Chaoa, Zhang Jiamingb, Wan Yuc, Wu Huia,c   

  1. a School of Chemistry and Chemical Engineering, Jiangsu Normal University, Jiangsu Key Laboratory of Green Synthesis of Functional Material, Xuzhou 221116;
    b Sihong County Bureau of Education, Sihong 223900;
    c Jiangsu Key Laboratory of Biotechnology on Medical Plant, Xuzhou 221116
  • Received:2013-11-05 Revised:2013-12-17 Published:2014-01-02
  • Supported by:

    Project supported by the Natural Science Foundation of the Jiangsu Higher Education Institutions of China (No. 10KJA430050) and the Natural Science Foundation of Jiangsu Normal University (No. 11XLA06).

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通过文献方法合成了具有较好平面共轭结构和较高电子云密度的5-氨基-2-芳基-3H-色烯[4，3，2-de][1，6]并二氮杂萘-4-腈（4）和5-氨基-2-芳基-3H-喹啉[4，3，2-de][1，6]并二氮杂萘-4-腈（6），研究了稠合环数、荧光助色团数量以及取代基类型对产物发光性能的影响，探索了其结构与发光性能之间的关系. 在发光性能构效关系指导下初步探究了化合物4对9种金属离子的识别，并从产物中筛选得到了具有进一步研究价值的、具开发为有机荧光材料潜质的产物.

关键词: 二氮杂萘, 荧光性能, 构效关系, 应用

5-Amino-2-aryl-3H-chromeno[4,3,2-de][1,6]naphthyridine-4-carbonitriles and 5-amino-2-aryl-3H-quinolino[4,3,2-de] [1,6]naphthyridine-4-carbonitriles were synthesized via literature method. The effect of the number of the fused ring, the amount of fluorescent auxochrome and the types of substituents on the luminescent properties of the products was investigated in detail to explore the relationships between their structure and luminescence properties. In the guidance of the structure-luminescence relationship, compound 4 was used as sensor to identify nine metal ions successfully. The products with potential researching and development value as organic fluorescent material were picked up.

Key words: naphthyridine, fluorescence properties, structure-luminescence relationship, application