有机化学 ›› 2015, Vol. 35 ›› Issue (7): 1399-1406.DOI: 10.6023/cjoc201502027 上一篇    下一篇

综述与进展

过渡金属催化法合成平面手性二茂铁衍生物的新进展

王艳芳a, 张安安b,c, 刘澜涛b, 康建勋c, 张富强a, 马文瑾a   

  1. a 山西师范大学化学与材料科学学院 临汾 041004;
    b 商丘师范学院化学化工学院 商丘 476000;
    c 郑州大学化学与分子工程学院 郑州 450052
  • 收稿日期:2015-02-23 修回日期:2015-03-24 发布日期:2015-03-27
  • 通讯作者: 刘澜涛, 马文瑾 E-mail:liult05@iccas.ac.cn;ma_w_j@163.com
  • 基金资助:

    国家自然科学基金(No. 21202095)、河南省高校科技创新人才基金(No. 14HASTIT016)和山西省自然科学基金(No. 2012011009-4)资助项目.

Recent Advances in Transition-Metal-Catalyzed Enantioselective Syntheses of Planar Chiral Ferrocenes

Wang Yanfanga, Zhang An'anb,c, Liu Lantaob, Kang Jianxunc, Zhang Fuqianga, Ma Wenjina   

  1. a School of Chemistry and Material Science, Shanxi Normal University, Linfen 041004;
    b College of Chemistry and Chemical Engineering, Shangqiu Normal University, Shangqiu 476000;
    c College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450052
  • Received:2015-02-23 Revised:2015-03-24 Published:2015-03-27
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21202095), the Program for Science & Technology Innovation Talents in Universities of Henan Province (No. 14HASTIT016) and the Natural Science Foundation of Shanxi Province (No. 2012011009-4).

平面手性二茂铁衍生物已经发展成为不对称催化反应中一类良好的手性配体和手性催化剂. 高效、高对映选择性的平面手性二茂铁衍生物合成方法研究是不对称催化研究的热点之一. 综述了近年来利用过渡金属催化法合成面手性二茂铁衍生物的进展.

关键词: 过渡金属催化, 合成, 面手性二茂铁衍生物, 不对称C-H活化

Planar chiral ferrocene derivatives have been proved to be effective ligands and catalysts in asymmetric catalysis. The study toward enantioselective synthesis of planar chiral ferrocenes became one of the high hot spots. In this paper, the recent advance in transition-metal-catalyzed menthods for the syntheses of planar chiral ferrocenes is reviewed.

Key words: transition-metal-catalyzed, synthesis, planar chiral ferrocenes, asymmetric C-H activation