有机化学 ›› 2016, Vol. 36 ›› Issue (12): 2843-2857.DOI: 10.6023/cjoc201605037 上一篇    下一篇

综述与进展

过渡金属氢化物在CO2活化和功能化反应中的应用

仉花, 孙宏建, 李晓燕   

  1. 山东大学化学与化工学院 教育部特种功能聚集体材料重点实验室 济南 250199
  • 收稿日期:2016-05-20 修回日期:2016-07-19 发布日期:2016-08-12
  • 通讯作者: 李晓燕 E-mail:xli63@sdu.edu.cn
  • 基金资助:

    国家自然科学基金(No. 21372143)资助项目.

Application of Transition Metal Hydrides in the Activation and Functionalization of CO2

Zhang Hua, Sun Hongjian, Li Xiaoyan   

  1. School of Chemistry and Chemical Engineering, Key Laboratory of Special Functional Aggregated Materials, Ministry of Education, Shandong University, Jinan 250199
  • Received:2016-05-20 Revised:2016-07-19 Published:2016-08-12
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21372143).

综述了Fe、Ru、Ir和Ni等过渡金属的氢化物在CO2活化、氢化、硼氢化和硅氢化反应中的应用,重点阐述了CO2氢化、硼氢化和硅氢化反应的反应机理及反应条件的优化.

关键词: 过渡金属氢化物, CO2, 活化, 氢化, 硼氢化, 硅氢化

The application of transition metal hydrides, such as hydrides of Fe, Ru, Ir and Ni, in the activation, hydrogenation, hydroboration and hydrosilation of CO2 is reported. And the mechanism and the reaction conditions of hydrogenation, hydrob-oration and hydrosilation of CO2 are described especially.

Key words: transition metal hydrides, CO2 activation, hydrogenation, hydroboration, hydrosilation