铜催化烯烃的不对称加成硼化反应研究进展

doi:10.6023/cjoc201609005

摘要/Abstract

铜催化烯烃的不对称加成硼化是构建手性碳硼键的有效方法，成为近年来有机化学的研究热点之一.从烯烃底物类型及反应类型的角度出发，总结了铜催化的烯烃的不对称加成硼化反应的研究进展.介绍了硼氢化反应及其串联反应以及包含硼化的双官能团化反应，以及以上反应的机理及发展现状，并对今后铜催化烯烃的不对称加成硼化反应的发展方向进行了展望.

关键词: 铜, 烯烃, 不对称催化, 加成硼化, 串联反应

The Cu-catalyzed asymmetric addition of borons to olefins is an efficient method to the construct chiral C-B bonds and has therefore gained much attention over recent years. This review describes recent research progress concerning Cu-catalyzed asymmetric additions of borons to olefins on the view of the types of olefin substrates and reactions. Such reactions include hydroborations, cascade reactions, difunctionalization reactions, and their associated mechanisms and developments. Additionally, research trends of this area are also discussed.

Key words: Cu, olefin, asymmetric catalysis, addition of boron, cascade reactions

引用此文

刘媛媛, 张万斌. 铜催化烯烃的不对称加成硼化反应研究进展[J]. 有机化学, 2016, 36(10): 2249-2271.

Liu Yuanyuan, Zhang Wanbin. Development of Cu-Catalyzed Asymmetric Addition of Boron to Olefin[J]. Chin. J. Org. Chem., 2016, 36(10): 2249-2271.

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