Chin. J. Org. Chem. ›› 2012, Vol. 32 ›› Issue (06): 1024-1040.DOI: 10.6023/cjoc1110313 Previous Articles     Next Articles

Reviews

偶氮二甲酸酯在有机合成中的研究进展

许孝良, 程国华, 李小年   

  1. 浙江工业大学化学工程与材料学院 杭州 310032
  • 收稿日期:2011-10-31 修回日期:2011-12-16 发布日期:2011-01-06
  • 通讯作者: 许孝良, 李小年 E-mail:xuxiaoliang@zjut.edu.cn; xnli@zjut.edu.cn
  • 基金资助:
    国家自然科学基金(No. 20872131)资助项目.

Application of Azodicarboxylates in Organic Synthesis

Xu Xiaoliang, Cheng Guohua, Li Xiaonian   

  1. College of Chemical Engineering and Material Science, Zhejiang University of Technology, Hangzhou 310032
  • Received:2011-10-31 Revised:2011-12-16 Published:2011-01-06
  • Supported by:
    Project supported by the National Natural Science Foundation of China (No. 20872131).

Azodicarboxylates, as versatile reagents, have been widely used in organic synthesis due to their unique electronic and structural properties. They have played important roles in organic synthesis such as Mitsunobu reaction, amination of carbonyl compounds and unsaturated hydrocarbons, synthesis of heterocyclic compounds. Besides these, azodicarboxylates can be used as oxidants for the dehydrogenation of alcohols and amines. Based on their previous applications, new progress of azodicarboxylates in synthetic chemistry in recent years is summarized and an outlook on their development is also given.

Key words: azodicarboxylates, organic synthesis, C—N bond formation