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Chin. J. Org. Chem. ›› 2012, Vol. 32 ›› Issue (9): 1736-1740.DOI: 10.6023/cjoc1203051 Previous Articles Next Articles
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李琴, 于海波, 关爱莹, 梁松军, 宋玉泉, 李斌
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“十二五”国家科技支撑计划(No.2011BAE06B01-05)及国家重点基础研究发展计划(973 计划)(Nos.2010CB735601, 2012CB724501)资助项目
Li Qin, Yu Haibo, Guan Aiying, Liang Songjun, Song Yuquan, Li Bin
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Project supported by the National Key Project of Scientific and Technology of China (No.2011BAE06B01-05) and the National Key Basic Research Program
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In search for new insecticides with high activity, broad-spectrum, low toxicity, favorable safety profile and no cross resistance to commercialized insecticides, eleven novel sulfinic esters containing dichloropropene were designed and synthesized from p-dihydroxybenzene in multiple steps. The structures of title compounds were identified by 1H NMR,13C NMR spectra and elemental analysis. The preliminary bioassays indicated that some of the target compounds showed good insecticidal activity against Plutella xylostella L. 3-[2,6-Dichloro-4-(3,3-dichloroallyloxy)phenoxyl]propyl n-hexyl sulfurous ester (7h) showed 80% mortality against Plutella xylostella L. at 10 mg/L, better than pyridaly.
Key words: dichloropropene, sulfinic esters, synthesis, insecticidal activity, Plutella xylostella L
Li Qin, Yu Haibo, Guan Aiying, Liang Songjun, Song Yuquan, Li Bin. Synthesis and Insecticidal Activity of Sulfinic Esters Containing Dichloropropene[J]. Chin. J. Org. Chem., 2012, 32(9): 1736-1740.
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[2] Wang, B.-Z.; Xu, X.-Y.; Tao, Y.-C. Chin. J. Pestic. Sci. 2010, 12, 429 (in Chinese). (王宝珠, 徐晓勇, 陶玉成, 农药学学报, 2010, 12, 429.)[3] Nauen, R.; Denhol, M. I. Arch. Insect Biochem. Physiol. 2005, 58, 200. [4] Tang, Z.-L.; Liu, H.-W.; Wang, X.-G.; Ou, X.-M.; Tang, R.-H.; Chen, Y.-B. Chin. J. Org. Chem. 2007, 27, 999 (in Chinese). (唐子龙, 刘汉文, 王晓光, 欧晓明, 唐仁和, 陈奕彬, 有机化学, 2007, 27, 999.)[5] Satto, S.; Isayama, S.; Sakamoto, N. J. Pestic. Sci. 2004, 29, 372. [6] Satto, S.; Ysoshioka, T.; Umeda, K. J. Pestic. Sci. 2006, 31, 335. [7] Covey, R. A.; Smith, A. E.; Hubbard, W. L. US 3179682, 1965 [Chem. Abstr. 1965, 63, 62731].