Bispyrazoline Fluorescent Probe for the Recognition of Cu2+ and Zn2+ with Different Fluorescence

doi:10.6023/cjoc201702024

Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (11): 3024-3030.DOI: 10.6023/cjoc201702024 Previous Articles Next Articles

Notes

通过不同荧光现象识别Cu²⁺和Zn²⁺的双吡唑啉荧光探针

杨云裳, 曹碧霞, 张应鹏, 董玉莹

兰州理工大学石油化工学院兰州 730050

收稿日期:2017-02-19 修回日期:2017-06-30 发布日期:2017-08-09
通讯作者: 杨云裳, 张应鹏 E-mail:yangyunshang@tom.com;yingpengzhang@126.com
基金资助:
甘肃省自然科学基金（No.2014GS03265）资助项目.

Bispyrazoline Fluorescent Probe for the Recognition of Cu²⁺ and Zn²⁺ with Different Fluorescence

Yang Yunshang, Cao Bixia, Zhang Yingpeng, Dong Yuying

School of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou 730050

Received:2017-02-19 Revised:2017-06-30 Published:2017-08-09
Contact: 10.6023/cjoc201702024 E-mail:yangyunshang@tom.com;yingpengzhang@126.com
Supported by:
Project supported by the Natural Science Foundation of Gansu Province (No. 2014GS03265).

1. Bispyrazoline Fluorescent Probe for the Recognition of Cu²⁺ and Zn²⁺ with Different Fluorescence.PDF(469KB)

Abstract

A bifunctional fluorescent probe 1,1'-(5,5'-(6,6'-dihydroxy-5,5'-dimethoxybiphenyl-3,3'-diyl)bis(3-(2-hydroxy-phenyl)-1H-pyrazole-5,1(4H,5H)-diyl))diethanone (C1) based on bispyrazoline was designed and synthesized. The structure of C1 was confirmed by ¹H NMR, ¹³C NMR, MS and elemental analysis. The spectroscopic behavior toward metal ions has been investigated by the absorption and fluorescence methods. It exhibited high sensitivity and selectivity for detecting Cu²⁺ and Zn²⁺ over other commonly coexistent metal ions in 4-(2-hydroxyethyl)-1-piperazine ethanesulfonic acid (HEPES) buffer solution[V(MeOH):V(H₂O)=1:1, 20 mol·L^-1, pH=7.4] and it has the capability to differentiate target ions with different flu-orescence.

Key words: bispyrazoline, bifunctional, fluorescent probe, copper ion, zinc ion

Cite this article

Yang Yunshang, Cao Bixia, Zhang Yingpeng, Dong Yuying. Bispyrazoline Fluorescent Probe for the Recognition of Cu²⁺ and Zn²⁺ with Different Fluorescence[J]. Chin. J. Org. Chem., 2017, 37(11): 3024-3030.

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通过不同荧光现象识别Cu²⁺和Zn²⁺的双吡唑啉荧光探针

Bispyrazoline Fluorescent Probe for the Recognition of Cu²⁺ and Zn²⁺ with Different Fluorescence

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通过不同荧光现象识别Cu2+和Zn2+的双吡唑啉荧光探针