Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (2): 432-442.DOI: 10.6023/cjoc201709016 Previous Articles     Next Articles



孔胜男, Abaid Ullah Malik, 钱雪峰, 舒谋海, 肖文德   

  1. 上海交通大学化学化工学院 上海 200240
  • 收稿日期:2017-09-09 修回日期:2017-10-18 发布日期:2017-10-31
  • 通讯作者: 舒谋海
  • 基金资助:


C-C Coupling Reactions in Water Catalyzed by Palladium

Kong Shengnan, Malik Abaid Ullah, Qian Xuefeng, Shu Mouhai, Xiao Wende   

  1. School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240
  • Received:2017-09-09 Revised:2017-10-18 Published:2017-10-31
  • Contact: 10.6023/cjoc201709016
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21271129).

A microporous organic polymer bearing 2, 2'-bipyridine functional group (MOP-bipy), has been synthesized. After treating with Pd (CH3CN)2Cl2, a composite material Pd/MOP-bipy was obtained. The materials have been characterized by 13C CP/MAS NMR, FT-IR, PXRD, SEM, TEM, nitrogen adsorption and thermogravimetric (TG) techniques. The content and valence of palladium in Pd/MOP-bipy have been determined by ICP and XPS. The composite material Pd/MOP-bipy exhibits excellent catalytic activity for Suzuki-Miyaura reaction in water and Sonogashira coupling reaction in methanol/water. The catalyst can be recycled at least five times without significant loss of the activity.

Key words: microporous organic polymer, heterogeneous catalysis, palladium, Suzuki-Miyaura coupling, Sonogashira coupling