Chinese Journal of Organic Chemistry ›› 2024, Vol. 44 ›› Issue (3): 840-870.DOI: 10.6023/cjoc202310034 Previous Articles     Next Articles

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有机光电催化合成研究进展

叶增辉, 刘华清, 张逢质*()   

  1. 杭州医学院药学院 杭州 310053
  • 收稿日期:2023-10-03 修回日期:2023-12-28 发布日期:2024-04-02
  • 基金资助:
    国家自然科学基金(22301055)

Recent Advances in Organic Electrophotocatalytic Synthesis

Zenghui Ye, Huaqing Liu, Fengzhi Zhang()   

  1. School of Pharmacy, Hangzhou Medical College, Hangzhou 310053
  • Received:2023-10-03 Revised:2023-12-28 Published:2024-04-02
  • Contact: *E-mail: zhangfengzhi@zjut.edu.cn
  • Supported by:
    National Natural Science Foundation of China(22301055)

Organic electrophotocatalysis synthesis is recognized as a powerful and scalable methodology for organic synthesis combining photocatalysis and electrolysis synthesis. However, the research in organic electrophotocatalytic synthesis is still in an early stage. In recent years, with the emergence of this strategy, an increasing number of reports have demonstrated the viability and potential of this new methodology to achieve unprecedented transformations. By harnessing light energy and electric energy as driving forces for the reaction, without relying on stoichiometric oxidants or reductants, it enables effective and highly selective redox reactions under relatively mild conditions. Consequently, it finds wide applications in various reaction systems including redox and cross coupling reactions. A comprehensive overview of the latest advancements in organic electrophotocatalysis synthesis in recent years while categorizing the reactions based on their bonding types is provided. The reaction mechanism, advantages and characteristics are also introduced. Finally, the future development direction of organic electrophotocatalytic synthesis is prospected.

Key words: organic electrophotocatalysis, electrochemical synthesis, photochemical synthesis, synergistic catalysis