Polymer-bonded metalloporphyrin-catalyzed hydroxylation of alkane

Chin. J. Org. Chem. ›› 1995, Vol. 15 ›› Issue (5): 520-524. Previous Articles Next Articles

Original Articles

高分子键联金属卟啉的合成及催化性能的研究

郑维忠;曾庆平;王先元

中国科学院成都有机化学研究所;中国科学院上海有机化学研究所;中国科学院金属有机化学开放实验室

发布日期:1995-10-25

Polymer-bonded metalloporphyrin-catalyzed hydroxylation of alkane

ZHENG WEIZHONG;ZENG QINGPING;WANG XIANYUAN

Published:1995-10-25

Abstract

Two porous polymer-bonded porphyrins were prepared by amin linkage of meso-tatrakis(4-pyridyl) porphyrin and meso-trtrakis (4-aminophenyl) porphyrin with polystyrene, respectively. Their Mn(Ⅲ), Fe(Ⅲ) Complexes were obtained from incorporating metal ions into porphyrin-containing polymer. It was found that M[tetrakis (4-pyridy) porphyrin] (M=Mn(Ⅲ), Fe(Ⅲ)) were effective catalysts for hydroxylation of alkane by PhIO.

Key words: ULTRAVIOLET SPECTROPHOTOMETRY, HYDROXYLATION, PYRIDINE P, PORPHYRIN, MANGANESE COMPLEX, NETWORK POLYMER, METAL COMPLEX, ELEMENTAL ANALYSIS, HEXANE, POLYSTYRENE

CLC Number:

O627

Cite this article

ZHENG WEIZHONG;ZENG QINGPING;WANG XIANYUAN. Polymer-bonded metalloporphyrin-catalyzed hydroxylation of alkane[J]. Chin. J. Org. Chem., 1995, 15(5): 520-524.

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高分子键联金属卟啉的合成及催化性能的研究

Polymer-bonded metalloporphyrin-catalyzed hydroxylation of alkane

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