Chin. J. Org. Chem. ›› 1995, Vol. 15 ›› Issue (6): 642-646. Previous Articles    

Original Articles

极化效应指数与脂肪族胺、醇和醚气相碱性的关系

曹晨忠   

  1. 湘潭师范学院化学系
  • 发布日期:1995-12-25

Relation between the polarizability effect index and the gas phase basicity of fatty amine, alcohol and ether

CAO CHENZHONG   

  • Published:1995-12-25

It can be expressed as the function of the atomic charge qx (X=N or O atom) and the Polarizability Effect Index (PEI) of alkyl group for the gas phase Proton Affinity (PA) of fatty amine, alcohol and ether Here, the a, b and c are empirical constants. The results of regression analysis showed that above equation is a good expression for the gas basicity change rule of amine, alcohol and ether.

Key words: PROTONS, ETHER, ALCOHOL, ALIPHATIC AMINES

CLC Number: