Low-valent titanium induced reductive coupling reaction of acyl chlorides with aliphatic ketones

Chin. J. Org. Chem. ›› 1996, Vol. 16 ›› Issue (2): 165-168. Previous Articles Next Articles

Original Articles

低价钛引起的酰氯与脂肪酮的还原偶联反应

史达清;周龙虎;戴桂元;陈伟兴

徐州师范学院化学系;南京大学化学系

发布日期:1996-04-25

Low-valent titanium induced reductive coupling reaction of acyl chlorides with aliphatic ketones

SHI DAQING;ZHOU LONGHU;DAI GUIYUAN;CHEN WEIXING

Published:1996-04-25

Abstract

The intermolecular reductive cross-coupling reaction of acyl chloride with two equivalents of aliphatic ketone induced by TiCl4-Zn reagent affords alkene.

Key words: ALIPHATIC KETONES, INFRARED SPECTROPHOTOMETRY, ACYL CHLORIDES, COUPLING REACTION, ELEMENTAL ANALYSIS, ALKENE, REDUCTION REACTION, NMR SPECTROMETRY, REACTION MECHANISM

CLC Number:

O621

Cite this article

SHI DAQING;ZHOU LONGHU;DAI GUIYUAN;CHEN WEIXING. Low-valent titanium induced reductive coupling reaction of acyl chlorides with aliphatic ketones[J]. Chin. J. Org. Chem., 1996, 16(2): 165-168.

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低价钛引起的酰氯与脂肪酮的还原偶联反应

Low-valent titanium induced reductive coupling reaction of acyl chlorides with aliphatic ketones

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