Chin. J. Org. Chem. ›› 1997, Vol. 17 ›› Issue (4): 362-364. Previous Articles     Next Articles

Original Articles

手性胶束的不对称诱导作用不对称苯偶姻缩合反应

张永敏;孙培培   

  1. 杭州大学化学系
  • 发布日期:1997-08-25

The asymmetric induction of chiral micelle asymmetric benzion condensation

ZHANG YONGMIN;SUN PEIPEI   

  • Published:1997-08-25

Micellar system can be used as a simple analogue to mimic enzyme. Chiral micelle has asymmetric induction to some reactions. In micelles formed from (1R,2S)-(-)-N-dodecyl-N-methylephedrine bromide and (1R,2S)-(-)-N-hexadecyl-N-methylepedrine bromide, via benzion condensation of arylaldehyde, optically active products were obtained.

Key words: CHIRALITY, MICELLE, KETONE P, C12 COMPOUNDS, HYDROXYL COMPOUNDS, BROMIDE, DIPHENYLHYDROXYETHANONE P, C16 COMPOUNDS, SURFACTANTS, CONDENSATION REACTION

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