Synthesis of some new phoshonyl substituted alicyclic compounds and enantiomer resolution

Chin. J. Org. Chem. ›› 1998, Vol. 18 ›› Issue (2): 119-123. Previous Articles Next Articles

Original Articles

新型膦酰基取代的脂环化合物的合成研究及手性拆分

王永梅;张慧萍;卫芳;李金亮;王磊;孟继本

南开大学化学系;云南师范大学化学系

发布日期:1998-04-25

Synthesis of some new phoshonyl substituted alicyclic compounds and enantiomer resolution

WANG YONGMEI;ZHANG HUIPING;WEI FANG;LI JINLIANG;WANG LEI;MENG JIBEN

Published:1998-04-25

Abstract

In this article Diels-Alder reaction of ethyldiyl-bis(diphenyl phosphine oxide) with substituted cyclopentadiene was studied. Four new organophosphorous ring compounds were synthesized. By using (±)-dibenzoyltartaric acid as the resolution agent, racemic 9,10-dihydro-9,10-etheno-2,3-benzoanthracene-11,12-bis (diphenyl phosphine oxide) was resolved and two optical activity products were obtained.

Key words: MESOTOMY, ACETYLENE P, TARTARIC ACID P, CYCLOPENTADIENE P, CHIRALITY, DIPHENYL GROUP, ORGANIC SYNTHESIS, CYCLOADDITION REACTION, DIPHENYL GROUP, ORGANO PHOSPHORUS COMPOUNDS

CLC Number:

O627

Cite this article

WANG YONGMEI;ZHANG HUIPING;WEI FANG;LI JINLIANG;WANG LEI;MENG JIBEN. Synthesis of some new phoshonyl substituted alicyclic compounds and enantiomer resolution[J]. Chin. J. Org. Chem., 1998, 18(2): 119-123.

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新型膦酰基取代的脂环化合物的合成研究及手性拆分

Synthesis of some new phoshonyl substituted alicyclic compounds and enantiomer resolution

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