The study on synthesis and electrochemical properties of tetra(benzoylmethylthio)-tetrathiafulvalene

Chin. J. Org. Chem. ›› 1998, Vol. 18 ›› Issue (4): 320-323. Previous Articles Next Articles

Original Articles

四(苯甲酰甲硫基)四硫富瓦烯的合成及其有关电化学性质的研究

赵富录;王小刚;王建华

第四军医大学化学教研室;西北大学化学系

发布日期:1998-08-25

The study on synthesis and electrochemical properties of tetra(benzoylmethylthio)-tetrathiafulvalene

ZHAO FULU;WANG XIAOGANG;WANG JIANHUA

Published:1998-08-25

Abstract

The reaction of 4, 5-bis(benzoylmethylthio)-1, 3-dithio-2-thione with glycol gave the ketal, followed by coupling with P(OMe)~3, and hydrolysis to give tetra (benzoylmethylthio)-tetrathiafulvalene (TBMT-TTF). The electrochemical properties of the compound have been studied by cyclic voltammetry and UV-Vis spectroscopy. The incorporating carbonyl TTF could be prepared by this method.

Key words: METHYL THIO GROUP, PHOSPHOROUS ACID ESTER, CYCLOPENTENE P, THIOKETONE, KETAL, SULFUR HETEROCYCLICS COMPOUNDS, CYCLOVOLTAMGRAPH, ETHANEDIOL, ORGANIC SYNTHESIS, ULTRAVIOLET SPECTROPHOTOMETRY

CLC Number:

O621

Cite this article

ZHAO FULU;WANG XIAOGANG;WANG JIANHUA. The study on synthesis and electrochemical properties of tetra(benzoylmethylthio)-tetrathiafulvalene[J]. Chin. J. Org. Chem., 1998, 18(4): 320-323.

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四(苯甲酰甲硫基)四硫富瓦烯的合成及其有关电化学性质的研究

The study on synthesis and electrochemical properties of tetra(benzoylmethylthio)-tetrathiafulvalene

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