Chin. J. Org. Chem. ›› 1999, Vol. 19 ›› Issue (3): 255-261. Previous Articles     Next Articles

Original Articles

3-芳基-3-环己烯基丙酸酯衍生物的合成和晶体结构

屠树江;史达清;路再生;王苏惠;魏启华;戴桂元   

  1. 徐州师范大学化学系.徐州(221009)
  • 发布日期:1999-06-25

Synthesis and crystal structure of 3-aryl-3-cyclohexeneyl propanoic ester derivatives

Tu Shujiang;Shi Daqing;Lu Zaisheng;Wang Suhui;Wei Qihua;Dai Guiyuan   

  1. Xuzhou Teachers Coll, Dept Chem.Xuzhou(221009)
  • Published:1999-06-25

A series of 3-aryl-3-(5, 5-dimethyl-3-hydroxy-2-cyclohexene-1-one-2- yl) propanoic esters were synthesized by reaction between aromatic aldehydes, 5, 5-dimethyl-1, 3-cyclohexanedione and isopropylidene malonate catalyzed by KF-Al~2O~3 in alcohols. The structure of 4a was determined by X-ray analysis. A possible mechanism for this reaction is postulated.

Key words: CYCLOHEXANEDIONE, SYNTHESIS, X-RAY DIFFRACTION ANALYSIS, ALUMINIUM OXIDE, POTASSIUM FLUORIDE, PROPIONATE, AROMATIC ALDEHYDE, CYCLOHEXENYL GROUP, CRYSTAL STRUCTURE

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