Synthesis under Ultrasonic Catalysis and Structural Characterization Dinuclearof Zn(II)-Macroheterocyclic Complex

Chinese Journal of Organic Chemistry ›› 2004, Vol. 24 ›› Issue (3): 297-299. Previous Articles Next Articles

双核锌(II)大杂环配合物的超声催化合成和结构表征

李良学^*,a, 刘继德^a, 吴爱斌^a, 秦少雄^a, 李琴^a, 邓立志^b, 黄筱玲^b

^a 湖北长江大学化学系荆州 434104
^b 武汉大学化学与分子科学学院武汉 430072

收稿日期:2003-05-06 修回日期:2003-09-10 接受日期:2003-10-08 发布日期:2022-09-20
基金资助:
国家自然科学基金(No. 20172067)资助项目

Synthesis under Ultrasonic Catalysis and Structural Characterization Dinuclearof Zn(II)-Macroheterocyclic Complex

LI, Liang-Xue^*,a, LIU, Ji-De^a, WU, Ai-Bin^a, QIN, Shao-Xiong^a, LI, Qin^a, DENG, Li-Zhi^b, HUANG, Xiao-Ling^b

^a Department of Chemistry, Yangtze University, Jingzhou 434104
^b Department of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072

Received:2003-05-06 Revised:2003-09-10 Accepted:2003-10-08 Published:2022-09-20
Contact: *E-mail: zhaoguo@mail.sioc.ac.cn

Abstract

By ultrasonic catalysis a macroheterocyclic dinuclear complex of C₂₃H₁₉N₂SF₃O₂Zn(1)-Zn(2)C₈H₅SF₃O₂ was synthesized. The title compound was characterized by IR, ¹H NMR, ¹³C NMR, MS and elemental analysis. It was found that both Zn(1) complexing to1,5-diazo-8,12-dioxa-4-trifluoromethyl-2-(2-thiophenyl)-6,7,13,14-bibenzocyclotetradecane with dsp³ hybrid orbitals and Zn(2) complexing to2-(1,1,1-trifluoroaceyl) acetylthiophene with sp² hybrid orbitals produce atree-like dinuclear complex of Zn(II).

Key words: dinuclear Zn(II) complex, macroheterocyclic, ultrasonic catalysis, synthesis, structural characterization

Cite this article

LI, Liang-Xue, LIU, Ji-De, WU, Ai-Bin, QIN, Shao-Xiong, LI, Qin, DENG, Li-Zhi, HUANG, Xiao-Ling. Synthesis under Ultrasonic Catalysis and Structural Characterization Dinuclearof Zn(II)-Macroheterocyclic Complex[J]. Chinese Journal of Organic Chemistry, 2004, 24(3): 297-299.

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双核锌(II)大杂环配合物的超声催化合成和结构表征

Synthesis under Ultrasonic Catalysis and Structural Characterization Dinuclearof Zn(II)-Macroheterocyclic Complex

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