Chin. J. Org. Chem. ›› 2006, Vol. 26 ›› Issue (01): 1-8.     Next Articles

Review

钯催化的炔烃环三聚反应

周磊2,3,江焕峰*,1,黄精美1,唐金玉2,3   

  1. (1华南理工大学化学科学学院 广州 510640)
    (2中国科学院广州化学研究所 广州 510650)
    (3中国科学院研究生院 北京 100036)
  • 收稿日期:2004-11-30 修回日期:2005-05-11 发布日期:2005-12-31
  • 通讯作者: 江焕峰

Palladium-Catalyzed Cyclotrimerization of Alkynes

ZHOU Lei2,3,JIANG Huan-Feng*,1,HUANG Jin-Mei1,TANG Jin-Yu2,3   

  1. (1 College of Chemistry, South China University of Technology, Guangzhou 510640)
    (2 Guangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou 510650)
    (3 Graduate School of the Chinese Academy of Sciences, Beijing 100036)
  • Received:2004-11-30 Revised:2005-05-11 Published:2005-12-31
  • Contact: JIANG Huan-Feng

This review summarizes the recent progress of palladium-catalyzed cyclotrimerization of alkynes, mainly discussing the effects of ligands, solvents and substituents on chemo- and regio-selectivities. In addition, the mechanism and challenge of a novel [2+2+1] reaction are also introduced in this review.

Key words: cyclotrimerization, alkyne, palladium