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Chin. J. Org. Chem. ›› 2006, Vol. 26 ›› Issue (04): 551-555. Previous Articles     Next Articles

Reports

取代1,1'-联-2-萘酚在铜胺络合物催化作用下的氧化反应

王秀珍，陈泳，汪波，庞冀燕，许遵乐*   

  1. (中山大学化学与化学工程学院 广州 510275)
  • 收稿日期:2005-07-12 修回日期:2005-10-28 发布日期:2006-03-31
  • 通讯作者: 许遵乐

Catalytic Oxidation Reaction of Substituted 1,1′-Bi-2-naphthols with Copper-Amine Complex

WANG Xiu-Zhen,CHEN Yong,WANG Bo,PANG Ji-Yan,XU Zun-Le*   

  1. (School of Chemistry and Chemical Engineering, Zhongshan University, Guangzhou 510275)
  • Received:2005-07-12 Revised:2005-10-28 Published:2006-03-31
  • Contact: XU Zun-Le

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The complex of CuCl2•2H2O with small molecular amine as a catalyst for Domino reaction, which was a mimic to oxidoreductase, was reported. Substituted 1,1'-bi-2-naphthols were oxidized into dibenzoxanthenoids in the presence of O2. The structures of these compounds were characterized with 1H NMR, IR and FAB-MS spectra.

Key words: substituted 1,1'-bi-2-naphthol, synthesis, dibenzoxanthenoid, Domino reaction, >copper-amine complex