Study on Synthesis and Spectral Properties of Porphyrin-salen Compounds

Abstract

Three salen compounds: salen-OH, Cl-salen-OH and t-Bu-salen-OH with hydroxyl group were synthesized. By salen-OH and t-Bu-salen-OH with 5,10,15-triphenyl-20-mesohydroxylphenylporphyrin (HPTPP) as a starting material, respectively, a series of novel porphyrin-salen compounds: HPC₆S (1), HPC₁₀S (2), HPC₆S' (3) and HPC₁₀S' (4) and their corresponding zinc(II) porphyrin-salen complexes: ZnPC₆S (Zn-1), ZnPC₁₀S (Zn-2), ZnPC₆S' (Zn-3), ZnPC₁₀S' (Zn-4) were synthesized and char-acterized by elemental analysis, FTIR, ¹H NMR and UV-Vis spectra, where P denotes porphy-rin, S means salen and S' indicates t-Bu-salen.

Key words: synthesis, spectral property, porphyrin-salen compound

Cite this article

ZHAO Xiao-Jing*^,1,RUAN Wen-Juan²,ZHU Zhi-Ang²
JIN Li-Ming,FAN Sheng-Di. Study on Synthesis and Spectral Properties of Porphyrin-salen Compounds[J]. Chin. J. Org. Chem., 2006, 26(08): 1087-1092.

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卟啉-salen化合物的合成及谱学性质研究