Chin. J. Org. Chem. ›› 2006, Vol. 26 ›› Issue (11): 1562-1565. Previous Articles     Next Articles

Original Articles

含噻二唑基的对叔丁基杯[4]芳烃衍生物的合成及表征

赵邦屯*,a,王璐b,冶保献*,b   

  1. (a洛阳师范学院化学系 洛阳 471022)
    (b郑州大学化学系 郑州 450001)
  • 收稿日期:2006-02-06 修回日期:1900-01-01 发布日期:2006-10-27
  • 通讯作者: 冶保献

Synthesis and Characterization of p-tert-Butylcalix[4]arene Derivatives Containning Thiadiazole Functional Groups

ZHAO Bang-Tun*,a,WANG Lub,YE Bao-Xian*,b   

  1. (a Department of Chemistry, Luoyang Normal University, Luoyang, 471022)
    (b Department of Chemistry, Zhengzhou University, Zhengzhou, 450001)
  • Received:2006-02-06 Revised:1900-01-01 Published:2006-10-27
  • Contact: YE Bao-Xian

The p-tert-butylcalix[4]arene (1) was firstly alkylated with 1,2-dibromoethane and 1,3-dibro- mopropane to give calix[4]arene derivatives 2 and 3 in the presence of potassium carbonate, respectively. A series of p-tert-butylcalix[4]arene derivatives 4a4c, 5a5c which append thiadiazolidinyl groups at the lower rims were easily synthesized in good yields by the reaction of compounds 2 or 3 with 2-mercapto- thiadiazole. All new compounds were characterized by 1H NMR, 13C NMR, IR, MS spectra and elemental analysis.

Key words: synthesis, characterization, thiadiazole, calix[4]arene derivative