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Chin. J. Org. Chem. ›› 2009, Vol. 29 ›› Issue (06): 858-866. Previous Articles     Next Articles

Review

含卤素取代基四硫富瓦烯的合成与研究进展

李洪启*,a ; 宋燕西b ; 李秀梅c   

  1. (a东华大学化学化工与生物工程学院 上海 201620)
    (b东华大学环境科学与工程学院 上海 201620)
    (c内蒙古通辽职业学院理工系 通辽 028000)
  • 收稿日期:2008-01-25 修回日期:2008-10-14 发布日期:2009-06-20
  • 通讯作者: 李洪启

Advances in Synthesis and Research of Tetrathiafulvalenes Containing Halogen Substituent

Li, Hongqi*,a; Song, Yanxib ; Li, Xiumeic   

  1. (a College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620)
    (b College of Environmental Science and Engineering, Donghua University, Shanghai 201620)
    (c Department of Physics and Technology, Inner Mongolia Tongliao Vocational College, Tongliao 028000)

  • Received:2008-01-25 Revised:2008-10-14 Published:2009-06-20
  • Contact: Li, Hongqi

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The two main methods for the synthesis of tetrathiafulvalene (TTF) derivatives containing halogen substituent, namely the direct halogenation of TTF and its derivatives and the trialkyl phosphite-mediated coupling of halogenated 1,3-dithiole-2-thione (or 2-one) compounds are outlined briefly. Electrochemical, crystalline, and film-forming properties as well as applications to construction of donor-acceptor dyads, oli-gomeric TTF systems, TTF-containing cyclophanes, TTF-containing polymers, and other functionalized TTF systems are reviewed. The development trends in research on TTF derivatives containing halogen substituent are proposed.

Key words: halogen substituent, synthetic intermediate, synthesis, electrochemical property, tetrathiafulvalene