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Chin. J. Org. Chem. ›› 2001, Vol. 21 ›› Issue (12): 1137-1141. Previous Articles     Next Articles

N-取代-N'-(2', 3', 4', 6'-四-O-乙酰基-β-D-吡喃葡萄糖基) (酰)氨基硫脲 的合成

李明;文丽荣;景淑霞;张玉冰;杨华铮;张书圣   

  1. 南开大学元素有机化学研究所.天津(300071);青岛化工学院应用化学系.青岛 (266042);兰州大学应用有机化学国家重点实验室.兰州(730000)
  • 发布日期:2001-12-25

N-substituted-N'-(2', 3', 4', 6'-tetra-O-acetyl)-β- D- glucopyranosyl thiocarbamides and thiosemicarbazides

Li Ming;Wen Lirong;Jing Shuxia;Zhang Yubing;Yang Huazheng;Zhang Shusheng   

  1. Nankai Univ, Elementoorgan Chem Lab.Tianjin(300071);Qindao Inst Chem Technol, Dept Appl Chem.Qingdao(266042);Lanzhou Univ, State Key Lab Appl Organ Chem.Lanzhou(730000)
  • Published:2001-12-25

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The reaction of 2, 3, 4, 6-tetra-O-acetyl-β-D- glucopyranosyl isothiocynate (Ⅰ) with aroyl hydrazine(Ⅱ), 2-amino-5-alkyl/aryl-1, 3, 4-thiadiazoles (Ⅲ), 3-alkyl/aryl-4- amino-5-mercapto-1, 2, 4- triazoles (Ⅳ) or O, O-dialkyl (thio) phosphorohydrazidates (Ⅴ, Ⅵ) furnished twelve new products, which structures were assigned as 1a～ 1c, 2d～2e, 3f～3i, 4j～4k and 5l respectively (all with β- configuration) on the basis of EA and spectral data.

Key words: ISOTHIOCYANATE, THIOSEMICARBAZIDE, SPECTROMETRIC ANALYSIS, SULFOCARBAMIDES, SYNTHESIS

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