Chin. J. Org. Chem. ›› 2002, Vol. 22 ›› Issue (1): 1-10. Previous Articles     Next Articles

低价钒试剂促进的有机反应及其在有机合成中的应用

范学森;张永敏;张永敏   

  1. 河南师范大学化学系.新湘(453002);浙江大学西溪校区化学系.杭州(310027)
  • 发布日期:2002-01-25

Organic reactions mediated by low-valent vanadium reagents and their applications in organic synthesis

Fan Xuesen;Zhang Yongmin;Zhang Yongmin   

  1. Henan Normal Univ, Dept Chem.Xinxiang(453002);Zhejiang Univ, Xixi campus, Dept of chem.Hangzhou(310027);Shanghai Inst Organ Chem., CAS. Shanghai(200032)
  • Published:2002-01-25

Some organic reactions mediated by low-valent vanadium reagents and their applications in organic synthesis are reviewed with an emphasis on the carbon-carbon bond formation reactions such as reuctive coupling of alkyl halides, reductive coupling of aldehydes and ketones, deoxygenative alkylation and deoxygenatie coupling of carbonyl compounds. Those reactions that are mediated by catalytic amounts of low-valent vanadium reagents are given special attention.

Key words: CARBON-CARBON BOND, VANADIUM COMPOUNDS, CHEMICAL REACTION, ORGANIC SYNTHESIS, ACCELERATORS

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