Progress in Rhodium-Catalyzed Asymmetric 1,4-ConjugateAddition Reactions

Chin. J. Org. Chem. ›› 2007, Vol. 27 ›› Issue (07): 806-818. Previous Articles Next Articles

Review

铑催化不对称1,4-共轭加成反应的研究进展

王欢，杨定乔*，莫海洪

(华南师范大学化学与环境学院广州 510006)

收稿日期:2006-07-26 修回日期:1900-01-01 发布日期:2007-06-30
通讯作者: 杨定乔*，

Progress in Rhodium-Catalyzed Asymmetric 1,4-ConjugateAddition Reactions

WANG Huan,YANG Ding-Qiao*,MO Hai-Hong

(School of Chemistry and Environment, South China Normal University, Guangzhou 510006)

Received:2006-07-26 Revised:1900-01-01 Published:2007-06-30
Contact: YANG Ding-Qiao*

Abstract

Rhodium-catalyzed asymmetric 1,4-conjugate addition reaction is one of the most efficient methods for the carbon-carbon bond formation. In this paper, the recent progress in rhodium-catalyzed asymmetric 1,4-conjugate addition reactions is reviewed. Asymmetric 1,4-conjugate additions of α,β-unsaturated ketones, esters, amides, aldehydes, sulfones and so on with some nu-cleophiles are presented.

Key words: 1,4-conjugate addition, asymmetric, nucleophile, rhodium-catalyzed

Cite this article

WANG Huan,YANG Ding-Qiao*,MO Hai-Hong. Progress in Rhodium-Catalyzed Asymmetric 1,4-ConjugateAddition Reactions[J]. Chin. J. Org. Chem., 2007, 27(07): 806-818.

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铑催化不对称1,4-共轭加成反应的研究进展

Progress in Rhodium-Catalyzed Asymmetric 1,4-ConjugateAddition Reactions

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