Chin. J. Org. Chem. ›› 1990, Vol. 10 ›› Issue (6): 529-534. Previous Articles     Next Articles

Original Articles

聚醚键联的(P)-CP2TiCl2 络合物的合成及催化性能研究

刘以寅;荣建辉;玄镇爱;王者福;陈寿山   

  1. 南开大学元素有机化学研究所
  • 发布日期:1990-12-25

Study on the syntheses and catalytic properties of polyethers-linked (p)-CP2,TiCl2

LIU YIYIN;RONG JIANHUI;XUAN ZHENAI;WANG ZHEFU;CHEN SHOUSHAN   

  • Published:1990-12-25

Some new poly(epichlorohydrin)-Cp2TiCl2 derivatives (I) were synthesized by "one-pot" method. The catalytic property of I on the isomerization of allylbenzenes and the factors affecting the reaction were probed. It was proved by ESR that I showed "position-sepd. effect".

Key words: GAS CHROMATOGRAPHY, INFRARED SPECTROPHOTOMETRY, CHLORIDE, BENZENE P, ISOMERIZATION REACTION, POLYEPOXYCHLOROPROPANE, ELECTRON SPIN RESONANCE, NMR SPECTROMETRY, CYCLOPENTADIENE P, TITANIUM COMPLEX

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