Studies on the synthesis and properties of tetrapropionitrilylthiocnal- cogefulvalene

Abstract

A new electron donor tetrapropionitrilylthiochalcogefulvalene TPT-TTF (I) has been prepared It has been studied with cyclic voltammetry and showed clearly that it has two single electron transfer reversible oxidation- wave. TPT-TTF is more stable than TTF with respect to energy. It has been studied with electronic absorption spectra and manifested clearly that the energy difference between TPT-TTF's p-orbital is smaller than the one between BEDT-TTF's which has good elec. conductivity

Key words: THIOKETONE, ULTRAVIOLET SPECTROPHOTOMETRY, REACTION MECHANISM, PROTON MAGNETIC RESONANCE SPECTROMETRY, CYCLOVOLTAMGRAPH, ELEMENTAL ANALYSIS, DITHIOLE P, INFRARED SPECTROPHOTOMETRY, PROPANENITRILE P, ELECTRON TRANSITION

CLC Number:

O627

Cite this article

LIU YONGCHENG;YAO ZHONGQI. Studies on the synthesis and properties of tetrapropionitrilylthiocnal- cogefulvalene[J]. Chin. J. Org. Chem., 1990, 10(6): 535-538.

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