Synthesis and Properties of 1,1-Diamino-2,2-dinitroethylene

Chin. J. Org. Chem. ›› 2006, Vol. 26 ›› Issue (10): 1409-1413. Previous Articles Next Articles

Original Articles

1,1-二氨基-2,2-二硝基乙烯的合成与性能研究

付秋菠^a,b，舒远杰*^,b，黄奕刚^b，周向葛^c，张允湘^a

(^a四川大学化工学院成都 610065)
(^b中国工程物理研究院化工材料研究所绵阳 621900)
(^c四川大学化学学院成都 610064)

收稿日期:2005-10-17 修回日期:2006-04-05 发布日期:2006-09-19
通讯作者: 舒远杰

Synthesis and Properties of 1,1-Diamino-2,2-dinitroethylene

FU Qiu-Bo^a,b,SHU Yuan-Jie*^,b,HUANG Yi-Gang^b
ZHOU Xiang-Ge^c,ZHANG Yun-Xiang^a

(^a College of Chemical Engineering, Sichuan University, Chengdu 610065)
(^bInstitute of Chemical Materials, China Academy of Engineering Physics, Mianyang 621900)
(^cCollege of Chemistry, Sichuan University, Chengdu 610064)

Received:2005-10-17 Revised:2006-04-05 Published:2006-09-19
Contact: SHU Yuan-Jie

Abstract

FOX-7 (1,1-diamino-2,2-dinitroethylene) was synthesized starting from the raw material 2-methylpyrimidine-4,6-dione after nitration and hydrolyzation. The title compound was characterized by means of IR, MS, NMR spectra and elemental analysis. The main factors which affected the yield were analyzed. The single crystals of the product were obtained from recrystalization. The CAD4 Diffractometer was used to measure the unit cell parameters of its single crystal. The sensitivities of electrospark and impact for FOX-7 were studied and compared with that of RDX (hexahydro-1,3,5-trinitro-1,3,5-triazine), HMX (cyclotetramethylene tetranitramine) and TATB (triaminotrinitrobenzene). The results shows that the sensi-tivity of FOX-7 is lower than that of RDX, but higher than that of TATB. Compared with the recrystalized product, it is found that the surface topography and thermal properties of the raw FOX-7 have great effects on its properties. In this way, it can be improved and optimized.

Key words: synthesis, crystal, thermal property, FOX-7

Cite this article

FU Qiu-Bo,b,SHU Yuan-Jie*^,b,HUANG Yi-Gang^b
ZHOU Xiang-Ge^c,ZHANG Yun-Xiang^a. Synthesis and Properties of 1,1-Diamino-2,2-dinitroethylene[J]. Chin. J. Org. Chem., 2006, 26(10): 1409-1413.

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1,1-二氨基-2,2-二硝基乙烯的合成与性能研究

Synthesis and Properties of 1,1-Diamino-2,2-dinitroethylene

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[1]	Penghui Li, Qingyang Xie, Fuxian Wan, Yuanhong Zhang, Lin Jiang. Synthesis and Fungicidal Activity of Novel Substituted Pyrimidine-5-carboxamides Bearing Cyclopropyl Moiety [J]. Chinese Journal of Organic Chemistry, 2024, 44(2): 650-656.
[2]	Fakai Zou, Nengzhong Wang, Hui Yao, Hui Wang, Mingguo Liu, Nianyu Huang. Regio- and Stereo-selective Synthesis of 1β-/3R-Aryl Thiosugar [J]. Chinese Journal of Organic Chemistry, 2024, 44(2): 593-604.
[3]	Luyao Li, Zhongwen He, Zhenguo Zhang, Zhenhua Jia, Teck-Peng Loh. Application of Triaryl Carbenium in Organic Synthesis [J]. Chinese Journal of Organic Chemistry, 2024, 44(2): 421-437.
[4]	Qinggang Mei, Qinghan Li. Recent Progress of Visible Light-Induced the Synthesis of C(3) (Hetero)arylthio Indole Compounds [J]. Chinese Journal of Organic Chemistry, 2024, 44(2): 398-408.
[5]	Shihang Yu, Jiawei Liu, Biyu An, Qinghua Bian, Min Wang, Jiangchun Zhong. Asymmetric Synthesis of the Contact Sex Pheromone of Neoclytus acuminatus acuminatus (Fabricius) [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 301-308.
[6]	Weiqing Yang, Yanbing Ge, Yuanyuan Chen, Ping Liu, Haiyan Fu, Menglin Ma. Design and Synthesis of Fluorescent 1,8-Napthalimide Derivatives and Their Identification of Cysteine [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 180-194.
[7]	Qianfan Zhao, Yongzheng Chen, Shiming Zhang. Application and Mechanism Study of Carbon-Based Metal-Free Catalysts in Organic Synthesis [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 137-147.
[8]	Shan Chen, Zhilin Chen, Qiong Hu, Yanshuang Meng, Yue Huang, Pingfang Tao, Liru Lu, Guobao Huang. Recognition of Bis-thiourea Tweezers to Neutral Molecules in Non-Polar Solvent [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 277-281.
[9]	Huakun Wang, Xiaolong Ren, Yining Xuan. Study of the Halide Salt Catalyzed [3＋2] Cycloaddition of α,β-Epoxy Carboxylate with Isocyanate [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 251-258.
[10]	Yukun Jin, Baoyi Ren, Fushun Liang. Visible Light-Mediated Selective C—F Bond Cleavage of Trifluoromethyl Groups and Its Application in Synthesizing gem-Difluoro-Containing Compounds [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 85-110.
[11]	Cuiyun Ma, Hailan Luo, Fuhua Zhang, Dan Guo, Shuxing Chen, Fei Wang. Green Biosynthesis, Photophysical Properties and Application of 3-Pyrrolyl BODIPY [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 216-223.
[12]	Bozhen Wang, Jie Zhang, Chunhui Nian, Mingming Jin, Miaomiao Kong, Wulan Li, Wenfei He, Jianzhang Wu. Synthesis and Antitumor Activity of 3,4-Dichlorophenyl Amides [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 232-241.
[13]	Ruixia Cao, Yuping Jia. Synthesis and Biological Activity of Novel Pyrrolo[2,3-d]pyrimidine Derivatives Containing Coumarin [J]. Chinese Journal of Organic Chemistry, 2023, 43(9): 3304-3311.
[14]	Huanqing Li, Zhaohua Chen, Zujia Chen, Qiwen Qiu, Youcai Zhang, Sihong Chen, Zhaoyang Wang. Research Progress in Mercury Ion Fluorescence Probes Based on Organic Small Molecules [J]. Chinese Journal of Organic Chemistry, 2023, 43(9): 3067-3077.
[15]	Ran Zhou, Chunmei Yuan, Tao Zhang, Piao Mao, Yi Liu, Kaini Meng, Hui Xin, Wei Xue. Design, Synthesis and Bioactivity of Chalcone Derivative Containing Quinazolinone [J]. Chinese Journal of Organic Chemistry, 2023, 43(9): 3196-3209.