Advancements and Prospects of [2＋2] Cycloaddition to [60]Fullerene

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Chin. J. Org. Chem. ›› 2007, Vol. 27 ›› Issue (03): 313-321. Previous Articles Next Articles

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[60]富勒烯[2＋2]环加成反应的研究进展

朱玉兰*^,a,b，周书雨^b，曹丽^a，阚玉和^a

(^a淮阴师范学院化学系江苏省低维材料化学重点建设实验室淮安 223001)
(^b延边大学理学院化学系延吉 133002)

收稿日期:2006-01-26 修回日期:2006-05-19 发布日期:2007-02-13
通讯作者: 朱玉兰

Advancements and Prospects of [2＋2] Cycloaddition to [60]Fullerene

ZHU Yu-Lan*^,a,b,ZHOU Shu-Yu^b,CAO Li^a,KAN Yu-He^a

(^aJiangsu Key Laboratory for Chemistry of Low-Dimensional Materials, Department of Chemistry, Huaiyin Teacher's College, Huaian 223001)
(^b Department of Chemis-try, College of Science, Yanbian University, Yanji 133002)

Received:2006-01-26 Revised:2006-05-19 Published:2007-02-13

Contact: ZHU Yu-Lan

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Abstract

[2＋2] cycloaddition plays an important role in [60]fullerene chemistry. C₆₀ can undergo this reaction with a series of compounds containing unsaturated bonds, such as alkyne, alkene and their deriva-tives. In addition, some polymerizations of C₆₀ also follow this route. In this review the main emphasis is on the three following aspects: classic reaction, the main reagent as well as the reaction mechanism.

Key words: reaction mechanism, [2＋2] cycloaddition, [60]fullerene

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ZHU Yu-Lan*^,a,b,ZHOU Shu-Yu^b,CAO Li^a,KAN Yu-He^a ^{. Advancements and Prospects of [2＋2] Cycloaddition to [60]Fullerene[J]. Chin. J. Org. Chem., 2007, 27(03): 313-321.}

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[1]	Huanqing Li, Zhaohua Chen, Zujia Chen, Qiwen Qiu, Youcai Zhang, Sihong Chen, Zhaoyang Wang. Research Progress in Mercury Ion Fluorescence Probes Based on Organic Small Molecules [J]. Chinese Journal of Organic Chemistry, 2023, 43(9): 3067-3077.
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[3]	Yueling Liu, Xinxin Zhong, Ganbing Zhang. Density Functional Theory Study for Exploring the Mechanisms of the [3＋2] Cycloaddition Reactions between 1-R-3-Phenylpropylidenecyclopropane (R=Me/H) and Furfural Catalyzed by Pd(0) [J]. Chinese Journal of Organic Chemistry, 2023, 43(2): 660-667.
[4]	Tingting Liu, Yucai Hu, An Shen. Mechanism of Carbon-Carbon Coupling Reactions Catalyzed by Imine-Ligand-Assisted N-Heterocyclic Carbene Palladium Complexes [J]. Chinese Journal of Organic Chemistry, 2023, 43(2): 622-628.
[5]	Zexin Huang, Yuqiang Yin, Fengcheng Jia, Anxin Wu. Research Progress on C2—C3 Bond Cleavage of Indole and Its Derivatives [J]. Chinese Journal of Organic Chemistry, 2022, 42(7): 2028-2044.
[6]	Yubing Shi, Wenji Bai, Weihua Mu, Jiangping Li, Jiawei Yu, Bing Lian. Research Progress on Density Functional Theory Study of Palladium-Catalyzed C—H Functionalization to Form C—X (X=O, N, F, I, …) Bonds [J]. Chinese Journal of Organic Chemistry, 2022, 42(5): 1346-1374.
[7]	Youcai Zhu, Xinxin Ding, Li Sun, Zhen Liu. Advances in the Production of Acrylic Acid and Its Derivatives by CO₂/C₂H₄ Coupling [J]. Chinese Journal of Organic Chemistry, 2022, 42(4): 965-977.
[8]	Zheng Li, Yingchun Gu, Dazhen Xu, Xuening Fei, Lei Zhang. Density Functional Theory Study on the Mechanism of Organophosphine-Catalyzed [4+2] Cycloaddition Reaction [J]. Chinese Journal of Organic Chemistry, 2022, 42(3): 830-837.
[9]	Man Xu, Yuanzhi Xia. Mechanistic Understanding of Rh(III)-Catalyzed Redox-Neutral C—H Activation/Annulation Reactions of N-Phenoxyacetamides and Methyleneoxetanones [J]. Chinese Journal of Organic Chemistry, 2021, 41(8): 3272-3278.
[10]	Kai Yang, Meijuan Liu, Yu'na Zhang, Jiaqi Zhan, Luxuan Deng, Xuejie Zheng, Yongjun Zhou, Zhaoyang Wang. Progress in the Synthesis of Benzoheterocycles from 2-Halobenzamides [J]. Chinese Journal of Organic Chemistry, 2021, 41(6): 2175-2187.
[11]	Fengcheng Jia, Na Luo, Cheng Xu, Anxin Wu. Recent Advances in the Synthesis of Benzoheterocyclic Compounds Involving Isatins [J]. Chinese Journal of Organic Chemistry, 2021, 41(4): 1527-1542.
[12]	Liang Liu, Wenbo Liu, Dong-Mei Cui, Ming Zeng. Progress in the Synthesis of Aroyl Compounds [J]. Chinese Journal of Organic Chemistry, 2021, 41(11): 4289-4305.
[13]	Xu Xinming, Yang Hanlin, Li Wenzhong. Transition Metal-Free Direct C-H Bond Sulfenylation of Alkenes and Arenes [J]. Chinese Journal of Organic Chemistry, 2020, 40(7): 1912-1925.
[14]	Li Zhifeng, Wang Wenpeng, Wang Xicun, Quan Zhengjun. Mechanism of Synthesis of Phosphinecarboxamides by Reaction of Sodium Phosphaethynolate Anion and Amines under Acid-Free Conditions: Density Functional Theory Investigation [J]. Chinese Journal of Organic Chemistry, 2020, 40(6): 1563-1570.
[15]	Xu Xinming, Li Jiazhu, Wang Zuli. Recent Advances in Transition Metal-Free Sulfenylation of Indoles [J]. Chinese Journal of Organic Chemistry, 2020, 40(4): 886-898.