Synthesis and Photoluminescence Properties of Novel Bisphenylene Crown Ether Conjugated Quinolin-8-ol and Their Complexes

Chin. J. Org. Chem. ›› 2008, Vol. 28 ›› Issue (10): 1729-1734. Previous Articles Next Articles

Original Articles

二芳基大环冠醚共轭8-羟基喹啉的合成及光致发光性质

魏娜; 陈玉磊 ; 蒋腊生*; 张敏; 范鉴全; 黄伟聪; 陶敬奇

(华南师范大学化学与环境学院广州 510006)

收稿日期:2007-10-25 修回日期:2007-01-23 发布日期:2008-10-20
通讯作者: 蒋腊生

Synthesis and Photoluminescence Properties of Novel Bisphenylene Crown Ether Conjugated Quinolin-8-ol and Their Complexes

WEI, Na; CHEN, Yu-Lei; JIANG, La-Sheng* ; ZHANG, Min;
FAN, Jian-Quan ; HUANG, Wei-Cong ; TAO, Jing-Qi

(School of Chemistry and Environment, South China Normal University, Guangzhou 510006

Received:2007-10-25 Revised:2007-01-23 Published:2008-10-20
Contact: JIANG, La-Sheng

Abstract

Two novel bisphenylene crown ether conjugated quinolin-8-ol derivatives (7a, 7b) and their zinc complexes were designed and synthesized. The structures of 7a and 7b were identified by UV-Vis, 1H NMR, 13C NMR, IR and MS techniques. The photofluorescence properties of 7a, 7b and their zinc complexes in solution were also studied. Their luminescent properties indicate that the emission wavelengths of 7a and 7b are at 460 and 467 nm, having a significant red shift compared to 2-methyl-8-hydroxyquinoline. The zinc complexes have weak light-emission at 562 and 565 nm respectively.

Key words: fluorescence spectrum, synthesis, bisarylene crown ether, complex, hydroxyquinoline

Cite this article

WEI, Na; CHEN, Yu-Lei; JIANG, La-Sheng* ; ZHANG, Min;
FAN, Jian-Quan ; HUANG, Wei-Cong ; TAO, Jing-Qi
. Synthesis and Photoluminescence Properties of Novel Bisphenylene Crown Ether Conjugated Quinolin-8-ol and Their Complexes[J]. Chin. J. Org. Chem., 2008, 28(10): 1729-1734.

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二芳基大环冠醚共轭8-羟基喹啉的合成及光致发光性质

Synthesis and Photoluminescence Properties of Novel Bisphenylene Crown Ether Conjugated Quinolin-8-ol and Their Complexes

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