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Chin. J. Org. Chem. ›› 2009, Vol. 29 ›› Issue (11): 1762-1767. Previous Articles     Next Articles

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新型卟啉衍生物的合成、结构表征和电化学性质的研究

王顺      谷永红   

  1. (中国科学技术大学化学与材料科学学院 合肥 230026)
  • 收稿日期:2009-03-01 修回日期:2009-05-15 发布日期:2009-06-08
  • 通讯作者: 谷永红 E-mail:ygu01@ustc.edu.cn
  • 基金资助:

    国家级.国家自然科学基金

Synthesis, Structure Characterization of New Derivatives of Porphyrin and Study on Their Electrochemical Properties

Wang, Shun      Gu, Yonghong*   

  1. (Department of Chemistry, University of Science and Technology of China, Hefei 230026)
  • Received:2009-03-01 Revised:2009-05-15 Published:2009-06-08

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2004

Using [5-(4-bromophenyl)-10, 15, 20-triphenylporphinato]zinc(II) as the substrate, 5-(4’-amino-biphenyl-4-yl)-10,15, 20-triphenylporphyrin, [5-(4’-amino-biphenyl-4-yl)-10,15,20-triphenylporphinato]zinc(II) and [5-(4’-methylthio-biphenyl-4-yl)-10,15, 20-triphenylporphinato]zinc(II) were synthesized by Stille coupling method as a key step. The structures of all the products were characterized with Uv, ‘H NMR, IR, Ms, Fs spectra and electrochemical properties of some compounds were studied by cyclic voltammetry.

Key words: porphyrin derivative, synthesis, Stille coupling, structure characterization, fluorescence property, cyclic voltammetry