Chin. J. Org. Chem. ›› 2010, Vol. 30 ›› Issue (07): 968-980. Previous Articles     Next Articles

Reviews

分子内烯炔复分解反应研究进展

杨晓霞*12,张勇3,邵志宇2   

  1. (1东华大学生态纺织教育部重点实验室 上海 201620)
    (2东华大学化学化工与生物工程学院 生物医药研究室 上海 201620)
    (3上海开拓者化学管理有限公司 药物化学部 上海 201203)
  • 收稿日期:2009-07-20 修回日期:2009-12-01 发布日期:2009-12-16
  • 通讯作者: 杨晓霞 E-mail:xiaoxiayang@dhu.edu.cn

Progress in Intramolecular Enyne-Metathesis

Yang Xiaoxia*12 Zhang Yong3 Shao Zhiyu2   

  1. (1 Key Laboratory of Science & Technology of Eco-Textile, Donghua University, Ministry of Education, Shanghai 201620) (2 College of Chemistry, Chemical Engineering and Biotechnology, Donghua Universitry, Shanghai 201620) (3 Shanghai ChemExplorer Co., Ltd., Shanghai 201203)
  • Received:2009-07-20 Revised:2009-12-01 Published:2009-12-16

Enyne metathesis involves the transformation of alkene and alkyne to a 1,3-diene. Intramolecular enyne metathesis has been widely considered as one of the most powerful tools in synthesis of cylco-compound. The reaction mechanism, catalyst and the application of enyne metathesis are reviewed.

Key words: enyne, metathesis, ruthenium carbene, catalyst