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Chin. J. Org. Chem. ›› 2011, Vol. 31 ›› Issue (06): 881-885. Previous Articles     Next Articles

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1,5-二取代六氢三嗪-2-N-硝基亚胺的合成和杀虫活性的测定

薛思佳*，马旭波，步洪飞   

  1. (上海师范大学生命与环境科学学院化学系 上海 200234)
  • 收稿日期:2010-10-27 修回日期:2010-12-25 发布日期:2011-01-21
  • 通讯作者: 薛思佳 E-mail:sjxue@sh163.net;sjxue@sohu.com;sjxue@shnu.edu.cn

Synthesis and Insecticidal Activities of 1,5-Disubstituted- hexahydro-triazine-2-N-nitroimines

XUE Si-Jia, MA Xu-Bo, BU Hong-Fei   

  1. (College of Life and Environment Science, Shanghai Normal University, Shanghai 200234)
  • Received:2010-10-27 Revised:2010-12-25 Published:2011-01-21

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Twelve novel 1,5-disubstituted-hexahydrotriazine-2-N-nitroimines (2a～2l) were synthesized with N-nitro-S-methylisothiourea and substituted benzylamines as raw materials via nucleophilic substitution and Manich reactions in turn. Their structures were elucidated and confirmed by 1H NMR, IR spectra and elemental analysis. The preliminary insecticidal activity tests indicated that all the target compounds have preferable insecticidal activity at the concentration of 500 mg/L.

Key words: neonicotinoid, hexahydrotriazine, nitroimine, insecticidal activity, synthesis