Research on the Solvent-Free Synthesis of Imi-dazo-[4,5-f][1,10]-phenanthroline

Chin. J. Org. Chem. ›› 2011, Vol. 31 ›› Issue (08): 1286-1289. Previous Articles Next Articles

Notes

芳基咪唑并菲咯啉的无溶剂绿色合成研究

李郁锦*，黄焕明，高建荣，贾建洪，董华青，韩亮，盛卫坚

(浙江工业大学化学工程与材料学院绿色化学合成技术国家重点实验室培育基地杭州 310014)

收稿日期:2010-09-06 修回日期:2011-03-02 发布日期:2011-03-21
通讯作者: 李郁锦 E-mail:lyjzjut@zjut.edu.cn

Research on the Solvent-Free Synthesis of Imi-dazo-[4,5-f][1,10]-phenanthroline

LI Yu-Jin, HUANG Huan-Ming, GAO Jian-Rong, JIA Jian-Hong, DONG Hua-Qing, HAN Liang, SHENG Wei-Jian

(State Key Laboratory of Green Chemistry-Synthesis Technology, College of Chemical Engineering and Material Science, Zhejiang University of Technology, Hangzhou 310014)

Received:2010-09-06 Revised:2011-03-02 Published:2011-03-21
Contact: Yu-Jin Li E-mail:lyjzjut@zjut.edu.cn

A facile procedure for the synthesis of 2-phenyl-imidazo-[4,5-f][1,10]phenanthroline derivatives starting from 1,10-phenanthrolinedione, aromatic aldehyde and ammonium acetate was reported. By screening the different reaction conditions, the reactions were carried out with catalyst-free and solvent-free in good yields, environmental benign, as well as convenient operation. The corresponding imidazo-[4,5-f][1,10]- phenanthroline was obtained in good yield by the reaction of aromatic aldehyde with 1,10-phenanthrolinediore.

Key words: phenanthrolinedione, solvent-free mulling, catalyst-free, imidazo-[4,5-f][1,10] phenanthroline

Cite this article

LI Yu-Jin, HUANG Huan-Ming, GAO Jian-Rong, JIA Jian-Hong, DONG Hua-Qing, HAN Liang, SHENG Wei-Jian. Research on the Solvent-Free Synthesis of Imi-dazo-[4,5-f][1,10]-phenanthroline[J]. Chin. J. Org. Chem., 2011, 31(08): 1286-1289.

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芳基咪唑并菲咯啉的无溶剂绿色合成研究

Research on the Solvent-Free Synthesis of Imi-dazo-[4,5-f][1,10]-phenanthroline

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