Synthesis of Adamantane-Based Betaine and Quaternary Ammo-nium Surfactants

Chin. J. Org. Chem. ›› 2011, Vol. 31 ›› Issue (08): 1290-1294. Previous Articles Next Articles

Notes

金刚烷基甜菜碱型和季铵盐阳离子型表面活性剂的合成研究

蔡璐¹，郭建维*^,1，刘卅²，朱乐杰¹，关念云¹，崔英德¹，孙保兴³

(¹广东工业大学轻工化工学院广州 510006)
(²华南理工大学材料学学院广州 510640)
(³广州市瑞洋表面活性剂有限公司广州 511400)

收稿日期:2010-10-11 修回日期:2011-03-07 发布日期:2011-03-25
通讯作者: 蔡璐 E-mail:cailugg09@2008.sina.com

Synthesis of Adamantane-Based Betaine and Quaternary Ammo-nium Surfactants

Cai Lu¹ Guo Jianwei*^,1 Liu Sa² Zhu Lejie¹ Guan Nianyun¹ Cui Yingde¹ Sun Baoxing³

(¹Faculty of Chemical Engineering & Light Industry, Guangdong University of Technology, Guangzhou 510006)
(²College of Material Science & Engineering, South China Univer-sity of Technology, Guangzhou 510640)
(³ Guangzhou Rui Yang Surfactant Ltd., Guangzhou 511400)

Received:2010-10-11 Revised:2011-03-07 Published:2011-03-25
Contact: Lu CAI E-mail:cailugg09@2008.sina.com

N-(1-Adamantyl)-N,N-dimethylamine was synthesized by Eschweiler-Clarke methylation reaction of 1-adamantine and formaldehyde in presence of excess formic acid firstly. Then five adamantane-based surfactants, including N-(1-adamantyl)-N,N-dimethyl-betaine, N-(1-adamantyl)-N,N-dimethyl- butyl-1-ammonium bromide, N-(1-adamantyl)-N,N-dimethyloctyl-1-ammonium bromide, N-(1-adamantyl)- N,N-dimethyldodecyl-1-ammonium bromide and N-(1-adamantyl)-N,N-dimethyl-hexadecyl-1-ammonium bromide were prepared via quaternarization reactions of N-(1-adamantyl)-N,N-dimethylamine with the sodium chloroacetate, 1-bromobutane, 1-bromooctane, 1-bromododecane and 1-bromohexadecane, respectively. The structures of products were identified by elemental analysis, IR, ¹HNMR, etc.

Key words: adamantane, quaternary ammonium, surfactant, synthesis

CLC Number:

0622.2

Cite this article

CAI Lu, GUO Jian-Wei, LIU Sa, ZHU Le-Jie, GUAN Nian-Yun, CUI Ying-De, SUN Bao-Xing. Synthesis of Adamantane-Based Betaine and Quaternary Ammo-nium Surfactants[J]. Chin. J. Org. Chem., 2011, 31(08): 1290-1294.

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金刚烷基甜菜碱型和季铵盐阳离子型表面活性剂的合成研究

Synthesis of Adamantane-Based Betaine and Quaternary Ammo-nium Surfactants

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