Recent Advances in Transition-Metal-Catalyzed Enantioselective Syntheses of Planar Chiral Ferrocenes

doi:10.6023/cjoc201502027

Chin. J. Org. Chem. ›› 2015, Vol. 35 ›› Issue (7): 1399-1406.DOI: 10.6023/cjoc201502027 Previous Articles Next Articles

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过渡金属催化法合成平面手性二茂铁衍生物的新进展

王艳芳^a, 张安安^b,c, 刘澜涛^b, 康建勋^c, 张富强^a, 马文瑾^a

a 山西师范大学化学与材料科学学院临汾 041004;
b 商丘师范学院化学化工学院商丘 476000;
c 郑州大学化学与分子工程学院郑州 450052

收稿日期:2015-02-23 修回日期:2015-03-24 发布日期:2015-03-27
通讯作者: 刘澜涛, 马文瑾 E-mail:liult05@iccas.ac.cn;ma_w_j@163.com
基金资助:
国家自然科学基金(No. 21202095)、河南省高校科技创新人才基金(No. 14HASTIT016)和山西省自然科学基金(No. 2012011009-4)资助项目.

Recent Advances in Transition-Metal-Catalyzed Enantioselective Syntheses of Planar Chiral Ferrocenes

Wang Yanfang^a, Zhang An'an^b,c, Liu Lantao^b, Kang Jianxun^c, Zhang Fuqiang^a, Ma Wenjin^a

a School of Chemistry and Material Science, Shanxi Normal University, Linfen 041004;
b College of Chemistry and Chemical Engineering, Shangqiu Normal University, Shangqiu 476000;
c College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450052

Received:2015-02-23 Revised:2015-03-24 Published:2015-03-27
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21202095), the Program for Science & Technology Innovation Talents in Universities of Henan Province (No. 14HASTIT016) and the Natural Science Foundation of Shanxi Province (No. 2012011009-4).

Planar chiral ferrocene derivatives have been proved to be effective ligands and catalysts in asymmetric catalysis. The study toward enantioselective synthesis of planar chiral ferrocenes became one of the high hot spots. In this paper, the recent advance in transition-metal-catalyzed menthods for the syntheses of planar chiral ferrocenes is reviewed.

Key words: transition-metal-catalyzed, synthesis, planar chiral ferrocenes, asymmetric C-H activation

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Wang Yanfang, Zhang An'an, Liu Lantao, Kang Jianxun, Zhang Fuqiang, Ma Wenjin. Recent Advances in Transition-Metal-Catalyzed Enantioselective Syntheses of Planar Chiral Ferrocenes[J]. Chin. J. Org. Chem., 2015, 35(7): 1399-1406.

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过渡金属催化法合成平面手性二茂铁衍生物的新进展

Recent Advances in Transition-Metal-Catalyzed Enantioselective Syntheses of Planar Chiral Ferrocenes

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