Copper-Promoted Synthesis of Thiochromones Derivatives

doi:10.6023/cjoc201605032

Chin. J. Org. Chem. ›› 2016, Vol. 36 ›› Issue (11): 2715-2722.DOI: 10.6023/cjoc201605032 Previous Articles Next Articles

Articles

铜促进硫代色酮类化合物的合成研究

李明, 宁加彬, 于乐, 文丽荣

青岛科技大学化学与分子工程学院生态化工国家重点实验室培育基地青岛 266042

收稿日期:2016-05-17 修回日期:2016-06-12 发布日期:2016-07-07
通讯作者: 文丽荣 E-mail:wenlirong@qust.edu.cn
基金资助:
国家自然科学基金（Nos.21572110，21372137）和山东省自然科学基金（No.ZR2014BM006）资助项目.

Copper-Promoted Synthesis of Thiochromones Derivatives

Li Ming, Ning Jiabin, Yu Le, Wen Lirong

State Key Laboratory Base of Eco-Chemical Engineering, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042

Received:2016-05-17 Revised:2016-06-12 Published:2016-07-07
Supported by:
Project supported by the National Natural Science Foundation of China (Nos.21572110,21372137) and the Natural Science Foundation of Shandong Province (No.ZR2014BM006).

1. Copper-Promoted Synthesis of Thiochromones Derivatives.PDF(1701KB)

Abstract

A new methodology to high chemoselectively synthesize thiochromone derivatives from β-oxodithioesters and substituted o-bromoacetophenones promoted by CuI/1,10-phen system based on the substrate-design concept has been developed. This approach has advantages of simple and efficient operation, and high yields.

Key words: thiochromones, β-oxodithioesters, substituted o-bromoacetophenones, copper, Ullmann coupling reaction, synthesis

Cite this article

Li Ming, Ning Jiabin, Yu Le, Wen Lirong. Copper-Promoted Synthesis of Thiochromones Derivatives[J]. Chin. J. Org. Chem., 2016, 36(11): 2715-2722.

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铜促进硫代色酮类化合物的合成研究

Copper-Promoted Synthesis of Thiochromones Derivatives

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