Recent Advances on Alkyl-Heck Reaction

doi:10.6023/cjoc201702040

Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (5): 1088-1098.DOI: 10.6023/cjoc201702040 Previous Articles Next Articles

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烷基Heck反应研究进展

董旭^a,b, 侯永正^a, 孟凡威^a, 刘洪波^a, 刘会^a,b

a 湖南大学材料科学与工程学院长沙 410082;
b 山东理工大学化学与工程学院淄博 255049

收稿日期:2017-02-26 修回日期:2017-03-23 发布日期:2017-04-13
通讯作者: 刘会 E-mail:huiliu1030@sdut.edu.cn
基金资助:
中国博士后科学基金（No.2016M590736）和山东省博士后创新项目专项资金（No.201501002）资助项目.

Recent Advances on Alkyl-Heck Reaction

Dong Xu^a,b, Hou Yongzheng^a, Meng Fanwei^a, Liu Hongbo^a, Liu Hui^a,b

a College of Materials Science and Engineering, Hunan University, Changsha 410082;
b School of Chemical Engineering, Shandong University of Technology, Zibo 255049

Received:2017-02-26 Revised:2017-03-23 Published:2017-04-13
Contact: 10.6023/cjoc201702040 E-mail:huiliu1030@sdut.edu.cn
Supported by:
Project supported by the China Postdoctoral Science Foundation (No. 2016M590736) and the Special Funding for Postdoctoral Innovation Project of Shandong Province (No. 201501002).

Recently, palladium-catalyzed alkyl-Heck reaction causes more attentions due to the wide application in the construction of C(sp³)-C(sp²). This review gives an up-to-date overview of alkyl-Heck reaction involving palladium radical intermediates, which are sorted in two categories of intramolecular reactions and intermolecular reactions. For most of these transformations, the plausible mechanisms are demonstrated in details. Clarification of these issues is the key point for understanding the palladium radical involved alkyl-Heck reactions and developing new high performance methodologies.

Key words: Pd-catalyzed, radical, Heck reaction, alkyl halide

Cite this article

Dong Xu, Hou Yongzheng, Meng Fanwei, Liu Hongbo, Liu Hui. Recent Advances on Alkyl-Heck Reaction[J]. Chin. J. Org. Chem., 2017, 37(5): 1088-1098.

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烷基Heck反应研究进展

Recent Advances on Alkyl-Heck Reaction

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