Metallocene Catalyst Systems and Control over the Propylene Polymerization

doi:10.6023/cjoc201803047

Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (11): 2937-2992.DOI: 10.6023/cjoc201803047 Previous Articles Next Articles

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茂金属催化剂体系及其丙烯聚合性能调控

陈志康^a, 毛远洪^b, 曹育才^c, 梁胜彪^b, 宋莎^c, 倪晨^b, 刘振宇^b, 叶晓峰^c, 沈安^c, 朱红平^a

a 固体表面物理化学国家重点实验室厦门大学化学化工学院厦门 361005;
b 中国石化茂名石化公司茂名 525021;
c 聚烯烃催化技术与高性能材料国家重点实验室上海市聚烯烃催化技术重点实验室上海化工研究院上海 200062

收稿日期:2018-03-27 修回日期:2018-05-27 发布日期:2018-06-15
通讯作者: 梁胜彪, 朱红平 E-mail:liangshengb.mmsh@sinopec.com;hpzhu@xmu.edu.cn
基金资助:
中国石化茂名石化公司基金、聚烯烃催化技术与高性能材料国家重点实验室基金和上海市聚烯烃催化技术重点实验室基金（Nos.201501-PT-C01-005，沪CXY-2015-003，16DZ2270800，16DZ2290700）、国家自然科学基金（Nos.21473142，20673191）和教育部创新团队基金（No.IRT_14R31）资助项目.

Metallocene Catalyst Systems and Control over the Propylene Polymerization

Chen Zhikang^a, Mao Yuanhong^b, Cao Yucai^c, Liang Shengbiao^b, Song Sha^c, Ni Chen^b, Liu Zhenyu^b, Ye Xiaofeng^c, Shen An^c, Zhu Hongping^a

a State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005;
b Sinopec Maoming Petrochemical Company, Maoming 525011;
c State Key Laboratory of Polyolefins and Catalysis, Shanghai Key Laboratory of Catalysis Technology for Polyolefins, Shanghai Research Institute of Chemical Industry, Shanghai 200062

Received:2018-03-27 Revised:2018-05-27 Published:2018-06-15
Supported by:
Project supported by the Sinopec Maoming Petrochemical Company, the State Key Laboratory of Polyolefins and Catalysis and Shanghai Key Laboratory of Catalysis Technology for Polyolefins (Nos. 201501-PT-C01-005, CXY-2015-003, 16DZ2270800, 16DZ2290700), the National Natural Science Foundation of China (Nos. 21473142, 20673191), and the Program for Innovative Research Team of Education (No. IRT_14R31).

While the metallocene catalysts were widely used to produce the metallocene polypropylenes (mPP) in other countries, the traditional Ziegler-Natta catalyst has still been dominantly employed for manufacturing the polypropylenes (PP) in our country at current time. The property of the mPP appears more improved than that of the PP produced by the Ziegler-Natta catalyst, and the market demand for the mPP is worldwidely increasing every year. Therefore, it is urgent to develop the metallocene catalysts for the industrial use in domestic companies. The metallocene catalysts are of versatile structures, which are able to show more exact control over the propylene polymerization activity and the polypropylene stereostructures than the Ziegler-Natta catalyst, and thus catalyze to generate new PPs of the diverse structures. This manuscript will give a detailed summary on the metallocene catalysts so far reported. The important factors such as temperature, propylene pressure, catalyst concentration, cocatalyst types and so on will be illustrated, which all have significant influence on the catalytic reaction activity. The reaction mechanism will be discussed as well.

Key words: metallocene catalyst, propylene polymerization, reaction mechanism, structural control, stereostructure of the polypropylenes, structure and property correalation

Cite this article

Chen Zhikang, Mao Yuanhong, Cao Yucai, Liang Shengbiao, Song Sha, Ni Chen, Liu Zhenyu, Ye Xiaofeng, Shen An, Zhu Hongping. Metallocene Catalyst Systems and Control over the Propylene Polymerization[J]. Chin. J. Org. Chem., 2018, 38(11): 2937-2992.

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茂金属催化剂体系及其丙烯聚合性能调控

Metallocene Catalyst Systems and Control over the Propylene Polymerization

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