A Highly Sensitive and Selective “Off-On” Fluorescent Probe for Cu2+ Based on Rhodamine B Hydrazone

doi:10.6023/cjoc202005084

Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (9): 2798-2803.DOI: 10.6023/cjoc202005084 Previous Articles Next Articles

一种基于罗丹明B酰腙的具有高灵敏度和选择性的“Off-On”型Cu^2＋荧光探针

雷萌萌^a,b, 周起航^a,b, 杨莉^a,b, 许志红^a,b, 杨风岭^a

a 郑州大学化学学院郑州 450001;
b 许昌学院化工与材料学院河南许昌 461000

收稿日期:2020-05-29 修回日期:2020-07-02 发布日期:2020-07-09
通讯作者: 许志红, 杨风岭 E-mail:xuzhihong1980@yahoo.com;yangfengling2005@yahoo.com.cn
基金资助:
国家自然科学基金-河南联合基金（No.U1304202）、河南省高校科技创新人才计划（No.15HASTIT002）、河南省科技厅（No.192102310295）、河南省高校重点研究计划（No.19A150046）和许昌市重点（No.2019-JC-02）资助项目.

A Highly Sensitive and Selective “Off-On” Fluorescent Probe for Cu²⁺ Based on Rhodamine B Hydrazone

Lei Mengmeng^a,b, Zhou Qihang^a,b, Yang Li^a,b, Xu Zhihong^a,b, Yang Fengling^a

a College of Chemistry, Zhengzhou University, Zhengzhou 450001;
b College of Chemical and Materials Engineering, Xuchang University, Xuchang, Henan 461000

Received:2020-05-29 Revised:2020-07-02 Published:2020-07-09
Supported by:
Project supported by the Joint Program for Fostering Talents of National Natural Science Foundation of China and Henan Province (No. U1304202), the Program for Science and Technology Innovation Talents in Universities of Henan Province (No. 15HASTIT002), the Science and Technology Project of Henan Province (No. 192102310295), the Key Program in Universities of Henan Province (No. 19A150046), and the Key Program of Xuchang City (No. 2019-JC-02).

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Abstract

Ethyl 5-formyl-3,4-dimethyl-pyrrole-2-carboxylate and rhodamine B hydrazide were used to synthesize a rhodamine derivative R1. Notably, the as-synthesized R1 displayed great sensitivity and selectivity, which was utilized to be an off-on fluorescence probe for Cu²⁺ detectionin mediums that contained water. Besides, the Cu²⁺ ions limit of detection (LOD) was 0.201 μmol·L^-1, and R1 was able to sense Cu²⁺ by "naked-eye" according to the change in color to pink from colorless. In addition, Cu²⁺ detection was assessed within the actual water samples for testing the probe actual application.

Key words: fluorescent probe, rhodamine, pyrrole, Cu²⁺

Cite this article

Lei Mengmeng, Zhou Qihang, Yang Li, Xu Zhihong, Yang Fengling. A Highly Sensitive and Selective “Off-On” Fluorescent Probe for Cu²⁺ Based on Rhodamine B Hydrazone[J]. Chinese Journal of Organic Chemistry, 2020, 40(9): 2798-2803.

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一种基于罗丹明B酰腙的具有高灵敏度和选择性的“Off-On”型Cu^2＋荧光探针

A Highly Sensitive and Selective “Off-On” Fluorescent Probe for Cu²⁺ Based on Rhodamine B Hydrazone

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一种基于罗丹明B酰腙的具有高灵敏度和选择性的“Off-On”型Cu2＋荧光探针