A Seminaphthorhodafluor-Based Fluorescent Probe for H2S Detection and Its Application

doi:10.6023/cjoc202006001

Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (9): 2956-2962.DOI: 10.6023/cjoc202006001 Previous Articles Next Articles

一种基于半萘基罗丹明衍生物的H₂S荧光探针及其应用

陈卫星^a, 王婷^a, 张云飞^a, 李淑颖^a, 周宏伟^a, 贾延琳^b, 金洗郎^a

a 西安工业大学材料与化工学院西安 710021;
b 中南大学材料科学与工程学院长沙 410083

收稿日期:2020-06-02 修回日期:2020-06-24 发布日期:2020-07-17
通讯作者: 金洗郎, 贾延琳 E-mail:jinxilang_911@163.com;jiayanlin@126.com
基金资助:
国家自然科学基金（Nos.51603164，21807085）、陕西省自然科学基金（No.2018JQ2015）资助项目.

A Seminaphthorhodafluor-Based Fluorescent Probe for H₂S Detection and Its Application

Chen Weixing^a, Wang Ting^a, Zhang Yunfei^a, Li Shuying^a, Zhou Hongwei^a, Jia Yanlin^b, Jin Xilang^a

a School of Material and Chemical Engineering, Xi'an Technological University, Xi'an 710021;
b College of Materials Science and Engineering, Central South University, Changsha, 410083

Received:2020-06-02 Revised:2020-06-24 Published:2020-07-17
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 51603164, 21807085), and the Natural Science Foundation Research Project of Shaanxi Province (No. 2018JQ2015).

1. cjoc202006001.pdf(929KB)

Abstract

A novel colorimetric and long-wavelength fluorescent probe (SR) based on seminaphthorhodafluor dye was designed and synthesized, which was used to detect H₂S through the thiolysis reaction of dinitrophenyl ether and unique OFF-ON mechanism based on the spiro-ring of probe SR. The fluorescent intensity (635 nm) and absorbance (590 nm) changes exhibited an excellent linear relationship with the H₂S concentration ranging from 2.00 to 10.00 μmol/L and the detection limits were 0.50 and 1.00 μmol/L, respectively. Ions interference experiments showed that probe SR had an excellent anti-interference ability and could be used to detect H₂S in complex systems. The probe SR was further exploited for filter paper, hydrogel and Hela cells for the rapid and convenient detection of H₂S, which extended the applications of fluorescent probes for the detection of H₂S in chemistry and the environment.

Key words: long-wavelength, fluorescence, hydrogel, H₂S, probe

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Chen Weixing, Wang Ting, Zhang Yunfei, Li Shuying, Zhou Hongwei, Jia Yanlin, Jin Xilang. A Seminaphthorhodafluor-Based Fluorescent Probe for H₂S Detection and Its Application[J]. Chinese Journal of Organic Chemistry, 2020, 40(9): 2956-2962.

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一种基于半萘基罗丹明衍生物的H₂S荧光探针及其应用

A Seminaphthorhodafluor-Based Fluorescent Probe for H₂S Detection and Its Application

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一种基于半萘基罗丹明衍生物的H2S荧光探针及其应用