Chinese Journal of Organic Chemistry ›› 2021, Vol. 41 ›› Issue (9): 3652-3659.DOI: 10.6023/cjoc202104046 Previous Articles Next Articles
ARTICLES
任尚峰a, 王玉超a, 刘晋彪a,*(), 邱观音生a,b,*()
收稿日期:
2021-04-21
修回日期:
2021-05-20
发布日期:
2021-06-22
通讯作者:
刘晋彪, 邱观音生
基金资助:
Shangfeng Rena, Yuchao Wanga, Jinbiao Liua(), Guanyinsheng Qiua,b()
Received:
2021-04-21
Revised:
2021-05-20
Published:
2021-06-22
Contact:
Jinbiao Liu, Guanyinsheng Qiu
Supported by:
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Shangfeng Ren, Yuchao Wang, Jinbiao Liu, Guanyinsheng Qiu. Arylsulfonylative spiro-Tricyclization of N-Hydroxylethyl- N-arylpropiolamides[J]. Chinese Journal of Organic Chemistry, 2021, 41(9): 3652-3659.
Entry | Additive | Oxidant | Temp./℃ | Solvent | Yield b |
---|---|---|---|---|---|
1 | I2O5 | Oxone | 80 | 1,4-二氧六环 | 26% |
2 | I2O5 | (NH4)2S2O8 | 80 | 1,4-二氧六环 | 12% |
3 | I2O5 | 间氯过氧苯甲酸 | 80 | 1,4-二氧六环 | 15% |
4 | I2O5 | 过氧化二苯甲酰 | 80 | 1,4-二氧六环 | Trace |
5 | I2O5 | 过氧化二叔丁基 | 80 | 1,4-二氧六环 | 18% |
6 | TBAB | Oxone | 80 | 1,4-二氧六环 | ND |
7 | TBAI | Oxone | 80 | 1,4-二氧六环 | 50% |
8 | I2 | Oxone | 80 | 1,4-二氧六环 | NR |
9 | TBAI | Oxone | 80 | 1,2-二氯乙烷 | 36% |
10 | TBAI | Oxone | 80 | DMF | NR |
11 | TBAI | Oxone | 80 | 甲苯 | 53% |
12 | TBAI | Oxone | 80 | 乙腈 | 40% |
13 | TBAI (50 mol%) | Oxone | 80 | 甲苯 | 26% |
14 | TBAI | Oxone | r.t. | 甲苯 | Trace |
15 | TBAI | Oxone | 60 | 甲苯 | 25% |
16 | TBAI | Oxone | 100 | 甲苯 | 36% |
17 | TBAI | — | 80 | 甲苯 | NR |
Entry | Additive | Oxidant | Temp./℃ | Solvent | Yield b |
---|---|---|---|---|---|
1 | I2O5 | Oxone | 80 | 1,4-二氧六环 | 26% |
2 | I2O5 | (NH4)2S2O8 | 80 | 1,4-二氧六环 | 12% |
3 | I2O5 | 间氯过氧苯甲酸 | 80 | 1,4-二氧六环 | 15% |
4 | I2O5 | 过氧化二苯甲酰 | 80 | 1,4-二氧六环 | Trace |
5 | I2O5 | 过氧化二叔丁基 | 80 | 1,4-二氧六环 | 18% |
6 | TBAB | Oxone | 80 | 1,4-二氧六环 | ND |
7 | TBAI | Oxone | 80 | 1,4-二氧六环 | 50% |
8 | I2 | Oxone | 80 | 1,4-二氧六环 | NR |
9 | TBAI | Oxone | 80 | 1,2-二氯乙烷 | 36% |
10 | TBAI | Oxone | 80 | DMF | NR |
11 | TBAI | Oxone | 80 | 甲苯 | 53% |
12 | TBAI | Oxone | 80 | 乙腈 | 40% |
13 | TBAI (50 mol%) | Oxone | 80 | 甲苯 | 26% |
14 | TBAI | Oxone | r.t. | 甲苯 | Trace |
15 | TBAI | Oxone | 60 | 甲苯 | 25% |
16 | TBAI | Oxone | 100 | 甲苯 | 36% |
17 | TBAI | — | 80 | 甲苯 | NR |
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