Chinese Journal of Organic Chemistry ›› 2021, Vol. 41 ›› Issue (12): 4725-4731.DOI: 10.6023/cjoc202111014 Previous Articles Next Articles
Special Issue: 有机光催化虚拟合辑； 绿色合成化学专辑； 热点论文虚拟合集
ARTICLES
何宇航, 杨慧, 高冬旭, 马嘉慧, 邵亚敏, 安光辉*(
), 李光明*()
收稿日期:2021-11-06
修回日期:2021-12-11
发布日期:2021-12-15
通讯作者:
安光辉, 李光明
基金资助:
Yuhang He, Hui Yang, Dongxu Gao, Jiahui Ma, Yamin Shao, Guanghui An(), Guangming Li()
Received:2021-11-06
Revised:2021-12-11
Published:2021-12-15
Contact:
Guanghui An, Guangming Li
Supported by:Share
Yuhang He, Hui Yang, Dongxu Gao, Jiahui Ma, Yamin Shao, Guanghui An, Guangming Li. Visible Light-Mediated Metal-Free Decarboxylative Deuteration of Carboxylic Acid[J]. Chinese Journal of Organic Chemistry, 2021, 41(12): 4725-4731.
| Entry | Base | Solvent | Yieldb/% of 2a/3a |
|---|---|---|---|
| 1 | Cs2CO3 | DMSO | 63/— |
| 2c | Cs2CO3 | DMSO | 12/— |
| 3d | Cs2CO3 | DMSO | 5/— |
| 4e | Cs2CO3 | DMSO | 8/— |
| 5 | K2CO3 | DMSO | 6/— |
| 6 | CsOAc | DMSO | 28/— |
| 7 | CsF | DMSO | 55/— |
| 8 | CsHCO3 | DMSO | 22/— |
| 9f | Cs2CO3 | DMSO | 60/— |
| 10 | Cs2CO3 | DMF | 43/— |
| 11 | Cs2CO3 | MeCN | 34/— |
| 12 | Cs2CO3 | DCE | 27/— |
| 13 | Cs2CO3 | MeCOOEt | 9/— |
| 14 | Cs2CO3 | CH2Cl2 | 7/— |
| 15g | Cs2CO3 | DMSO | 5/20 |
| 16h | Cs2CO3 | DMSO | —/50 |
| 17h | CsOAc | DMSO | —/15 |
| 18h | CsF | DMSO | —/19 |
| 19h | Cs2CO3 | MeCN | —/16 |
| 20h | Cs2CO3 | DMF | —/18 |
| 21i | Cs2CO3 | DMSO | —/54 |
| Entry | Base | Solvent | Yieldb/% of 2a/3a |
|---|---|---|---|
| 1 | Cs2CO3 | DMSO | 63/— |
| 2c | Cs2CO3 | DMSO | 12/— |
| 3d | Cs2CO3 | DMSO | 5/— |
| 4e | Cs2CO3 | DMSO | 8/— |
| 5 | K2CO3 | DMSO | 6/— |
| 6 | CsOAc | DMSO | 28/— |
| 7 | CsF | DMSO | 55/— |
| 8 | CsHCO3 | DMSO | 22/— |
| 9f | Cs2CO3 | DMSO | 60/— |
| 10 | Cs2CO3 | DMF | 43/— |
| 11 | Cs2CO3 | MeCN | 34/— |
| 12 | Cs2CO3 | DCE | 27/— |
| 13 | Cs2CO3 | MeCOOEt | 9/— |
| 14 | Cs2CO3 | CH2Cl2 | 7/— |
| 15g | Cs2CO3 | DMSO | 5/20 |
| 16h | Cs2CO3 | DMSO | —/50 |
| 17h | CsOAc | DMSO | —/15 |
| 18h | CsF | DMSO | —/19 |
| 19h | Cs2CO3 | MeCN | —/16 |
| 20h | Cs2CO3 | DMF | —/18 |
| 21i | Cs2CO3 | DMSO | —/54 |
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